Charge-transfer complexes of iodine and inorganic anions in solution

Dan Meyerstein; Avner Treinin

doi:10.1039/tf9635901114

Charge-transfer complexes of iodine and inorganic anions in solution

Dan Meyerstein, Avner Treinin

Research output: Contribution to journal › Article › peer-review

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Abstract

In aqueous solution, iodine forms complexes with several anions including halides, CNS∼ and N^-₃. Their spectra and stability constants are determined. Energetic evidence is presented indicating that these are charge-transfer complexes, and that their characteristic intense absorption bands are due to electron transfer from the anion to iodine. The structure of polyhalides and their photochemistry are discussed.

Original language	English
Pages (from-to)	1114-1120
Number of pages	7
Journal	Transactions of the Faraday Society
Volume	59
DOIs	https://doi.org/10.1039/tf9635901114
State	Published - 1 Jan 1963
Externally published	Yes

ASJC Scopus subject areas

General Engineering
General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1039/tf9635901114

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title = "Charge-transfer complexes of iodine and inorganic anions in solution",

abstract = "In aqueous solution, iodine forms complexes with several anions including halides, CNS∼ and N-3. Their spectra and stability constants are determined. Energetic evidence is presented indicating that these are charge-transfer complexes, and that their characteristic intense absorption bands are due to electron transfer from the anion to iodine. The structure of polyhalides and their photochemistry are discussed.",

author = "Dan Meyerstein and Avner Treinin",

year = "1963",

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doi = "10.1039/tf9635901114",

language = "English",

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T1 - Charge-transfer complexes of iodine and inorganic anions in solution

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AU - Treinin, Avner

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N2 - In aqueous solution, iodine forms complexes with several anions including halides, CNS∼ and N-3. Their spectra and stability constants are determined. Energetic evidence is presented indicating that these are charge-transfer complexes, and that their characteristic intense absorption bands are due to electron transfer from the anion to iodine. The structure of polyhalides and their photochemistry are discussed.

AB - In aqueous solution, iodine forms complexes with several anions including halides, CNS∼ and N-3. Their spectra and stability constants are determined. Energetic evidence is presented indicating that these are charge-transfer complexes, and that their characteristic intense absorption bands are due to electron transfer from the anion to iodine. The structure of polyhalides and their photochemistry are discussed.

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U2 - 10.1039/tf9635901114

DO - 10.1039/tf9635901114

M3 - Article

AN - SCOPUS:37049053372

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EP - 1120

JO - Transactions of the Faraday Society

JF - Transactions of the Faraday Society

ER -

Charge-transfer complexes of iodine and inorganic anions in solution

Abstract

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