Charge-transfer complexes of iodine and inorganic anions in solution

Dan Meyerstein, Avner Treinin

Research output: Contribution to journalArticlepeer-review

48 Scopus citations

Abstract

In aqueous solution, iodine forms complexes with several anions including halides, CNS∼ and N-3. Their spectra and stability constants are determined. Energetic evidence is presented indicating that these are charge-transfer complexes, and that their characteristic intense absorption bands are due to electron transfer from the anion to iodine. The structure of polyhalides and their photochemistry are discussed.

Original languageEnglish
Pages (from-to)1114-1120
Number of pages7
JournalTransactions of the Faraday Society
Volume59
DOIs
StatePublished - 1 Jan 1963
Externally publishedYes

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