Chelating alkylidene ligands as pacifiers for ruthenium catalysed olefin metathesis

Yuval Vidavsky, Aviel Anaby, N. Gabriel Lemcoff

Research output: Contribution to journalReview articlepeer-review

94 Scopus citations

Abstract

Olefin metathesis catalysed by ruthenium has emerged at the frontier of modern synthetic chemistry. The desire to enhance catalyst stability, gain control over the catalytic process and deepen the understanding of the mechanisms of metathesis has yielded a class of latent ruthenium precatalysts of delayed initiation and with switchable activity. One of the main methodologies developed for this purpose has been the introduction of tethered carbene ligands. Herein we track the evolution of ruthenium based metathesis catalysts bearing chelated alkylidenes, from the early oxygen Hoveyda type benzylidenes to the latent sulphur containing complexes.

Original languageEnglish
Pages (from-to)32-43
Number of pages12
JournalDalton Transactions
Volume41
Issue number1
DOIs
StatePublished - 7 Jan 2012

Fingerprint

Dive into the research topics of 'Chelating alkylidene ligands as pacifiers for ruthenium catalysed olefin metathesis'. Together they form a unique fingerprint.

Cite this