Chemical synthesis of poly(5-carboxyindole) and poly(5-carboxyindole)/ carboxylated multiwall carbon nanotube nanocomposite

  • Leela Joshi
  • , Bhavana Gupta
  • , Rajiv Prakash

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

Carboxyl functionalized conducting polymer, poly(5-carboxyindole) and its uniform coating over carboxyl functionalized multiwall carbon nanotube (c-MWNT) are reported using in-situ chemical synthesis. c-MWNT is dispersed properly in ethanol along with monomer and adsorption of monomers over c-MWNT surfaces is achieved by acid base interactions (monomer and c-MWNT). Formation of polymer is confirmed by Nuclear Magnetic Resonance and interaction with c-MWNTs is investigated by Fourier Transform Infrared and thermal analysis. X-ray Diffraction and Scanning Electron Microscopy studies show tubular nanocomposite formation of uniform polymer wrapped nanotubes. Electrochemical study shows significant enhancement in conductivity and capacitance with a large decrease of charge transfer resistance in comparison to pure polymer.

Original languageEnglish
Pages (from-to)218-222
Number of pages5
JournalThin Solid Films
Volume519
Issue number1
DOIs
StatePublished - 29 Oct 2010
Externally publishedYes

Keywords

  • Chemical polymerization
  • Electrochemical technique
  • Multiwall carbon nanotube
  • Nanocomposite
  • Poly(5-carboxyindole)

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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