Chimeric supramolecular synthons in Ph2Te2(I2)Se

Yury V. Torubaev

doi:10.1107/S2053229620006166

Chimeric supramolecular synthons in Ph₂Te₂(I₂)Se

Yury V. Torubaev

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Iodination of Ph2Te2Se by molecular iodine is directed towards the Te atom and yields {diiodo[(phenyltellanyl)selanyl]-λ⁴-tellanyl}benzene, PhTeSeTeI2Ph or C12H10I2SeTe2. The molecule can be considered as a chimera of PhTeSeR, PhTeSeTePh and R′TeI2Ph fragments. The crystal structure features a complex interplay of the supramolecular synthons Te⋯π(Ph), Se⋯Te and I⋯Te, combining molecules into a three-dimensional framework. Their combination affords long-range supramolecular synthons which are fused in a way resembling the mythological chimera and could be defined as chimeric supramolecular synthons. The energies of the intermolecular interactions have also been calculated and analyzed.

Original language	English
Pages (from-to)	579-584
Number of pages	6
Journal	Acta crystallographica. Section C, Structural chemistry
Volume	76
DOIs	https://doi.org/10.1107/S2053229620006166
State	Published - 1 Jun 2020
Externally published	Yes

Keywords

chalcogenide
crystal structure
energy framework
halogen bonding
secondary bonding
supramolecular synthon
σ-hole

ASJC Scopus subject areas

Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1107/S2053229620006166

Cite this

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title = "Chimeric supramolecular synthons in Ph2Te2(I2)Se",

abstract = "Iodination of Ph2Te2Se by molecular iodine is directed towards the Te atom and yields \{diiodo[(phenyltellanyl)selanyl]-λ4-tellanyl\}benzene, PhTeSeTeI2Ph or C12H10I2SeTe2. The molecule can be considered as a chimera of PhTeSeR, PhTeSeTePh and R′TeI2Ph fragments. The crystal structure features a complex interplay of the supramolecular synthons Te⋯π(Ph), Se⋯Te and I⋯Te, combining molecules into a three-dimensional framework. Their combination affords long-range supramolecular synthons which are fused in a way resembling the mythological chimera and could be defined as chimeric supramolecular synthons. The energies of the intermolecular interactions have also been calculated and analyzed.",

keywords = "chalcogenide, crystal structure, energy framework, halogen bonding, secondary bonding, supramolecular synthon, σ-hole",

author = "Torubaev, \{Yury V.\}",

note = "Publisher Copyright: {\textcopyright} 2020 International Union of Crystallography.",

year = "2020",

month = jun,

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doi = "10.1107/S2053229620006166",

language = "English",

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journal = "Acta crystallographica. Section C, Structural chemistry",

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TY - JOUR

T1 - Chimeric supramolecular synthons in Ph2Te2(I2)Se

AU - Torubaev, Yury V.

PY - 2020/6/1

Y1 - 2020/6/1

N2 - Iodination of Ph2Te2Se by molecular iodine is directed towards the Te atom and yields {diiodo[(phenyltellanyl)selanyl]-λ4-tellanyl}benzene, PhTeSeTeI2Ph or C12H10I2SeTe2. The molecule can be considered as a chimera of PhTeSeR, PhTeSeTePh and R′TeI2Ph fragments. The crystal structure features a complex interplay of the supramolecular synthons Te⋯π(Ph), Se⋯Te and I⋯Te, combining molecules into a three-dimensional framework. Their combination affords long-range supramolecular synthons which are fused in a way resembling the mythological chimera and could be defined as chimeric supramolecular synthons. The energies of the intermolecular interactions have also been calculated and analyzed.

AB - Iodination of Ph2Te2Se by molecular iodine is directed towards the Te atom and yields {diiodo[(phenyltellanyl)selanyl]-λ4-tellanyl}benzene, PhTeSeTeI2Ph or C12H10I2SeTe2. The molecule can be considered as a chimera of PhTeSeR, PhTeSeTePh and R′TeI2Ph fragments. The crystal structure features a complex interplay of the supramolecular synthons Te⋯π(Ph), Se⋯Te and I⋯Te, combining molecules into a three-dimensional framework. Their combination affords long-range supramolecular synthons which are fused in a way resembling the mythological chimera and could be defined as chimeric supramolecular synthons. The energies of the intermolecular interactions have also been calculated and analyzed.

KW - chalcogenide

KW - crystal structure

KW - energy framework

KW - halogen bonding

KW - secondary bonding

KW - supramolecular synthon

KW - σ-hole

UR - https://www.scopus.com/pages/publications/85086008251

U2 - 10.1107/S2053229620006166

DO - 10.1107/S2053229620006166

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JO - Acta crystallographica. Section C, Structural chemistry

JF - Acta crystallographica. Section C, Structural chemistry

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