Cis, anti, cis‐Tricyclo[5.3.0.02,6]deca‐4,9‐dione

Arnon Shani; Zeev Tashma

doi:10.1002/hlca.19770600609

Cis, anti, cis‐Tricyclo[5.3.0.0^2,6]deca‐4,9‐dione

Arnon Shani, Zeev Tashma

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The chemical behavior and some physical properties (dipole moment, IR. vs. Raman spectra) of the titled compound are not fully consistent with a strictly centrosymmetric structure which might be expected for the anti configuration. The carbonyl groups are less reactive toward nucleophilic reagents and sp² → sp³ transformations as compared to cyclopentanone systems.

Original language	English
Pages (from-to)	1903-1914
Number of pages	12
Journal	Helvetica Chimica Acta
Volume	60
Issue number	6
DOIs	https://doi.org/10.1002/hlca.19770600609
State	Published - 1 Jan 1977

ASJC Scopus subject areas

Catalysis
Biochemistry
Drug Discovery
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1002/hlca.19770600609

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title = "Cis, anti, cis‐Tricyclo[5.3.0.02,6]deca‐4,9‐dione",

abstract = "The chemical behavior and some physical properties (dipole moment, IR. vs. Raman spectra) of the titled compound are not fully consistent with a strictly centrosymmetric structure which might be expected for the anti configuration. The carbonyl groups are less reactive toward nucleophilic reagents and sp2 → sp3 transformations as compared to cyclopentanone systems.",

author = "Arnon Shani and Zeev Tashma",

year = "1977",

month = jan,

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doi = "10.1002/hlca.19770600609",

language = "English",

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journal = "Helvetica Chimica Acta",

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T1 - Cis, anti, cis‐Tricyclo[5.3.0.02,6]deca‐4,9‐dione

AU - Shani, Arnon

AU - Tashma, Zeev

PY - 1977/1/1

Y1 - 1977/1/1

N2 - The chemical behavior and some physical properties (dipole moment, IR. vs. Raman spectra) of the titled compound are not fully consistent with a strictly centrosymmetric structure which might be expected for the anti configuration. The carbonyl groups are less reactive toward nucleophilic reagents and sp2 → sp3 transformations as compared to cyclopentanone systems.

AB - The chemical behavior and some physical properties (dipole moment, IR. vs. Raman spectra) of the titled compound are not fully consistent with a strictly centrosymmetric structure which might be expected for the anti configuration. The carbonyl groups are less reactive toward nucleophilic reagents and sp2 → sp3 transformations as compared to cyclopentanone systems.

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U2 - 10.1002/hlca.19770600609

DO - 10.1002/hlca.19770600609

M3 - Article

AN - SCOPUS:0017649058

SN - 0018-019X

VL - 60

SP - 1903

EP - 1914

JO - Helvetica Chimica Acta

JF - Helvetica Chimica Acta

IS - 6

ER -

Cis, anti, cis‐Tricyclo[5.3.0.0^2,6]deca‐4,9‐dione

Abstract

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