Cl-37/Cl-35 isotope ratio analysis in perchlorate by ion chromatography/multi collector -ICPMS: Analytical performance and implication for biodegradation studies

Yevgeni Zakon, Zeev Ronen, Ludwik Halicz, Faina Gelman

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2 Scopus citations

Abstract

In the present study we propose a new analytical method for 37Cl/35Cl analysis in perchlorate by Ion Chromatography(IC) coupled to Multicollector Inductively Coupled Plasma Mass Spectrometry (MC-ICPMS). The accuracy of the analytical method was validated by analysis of international perchlorate standard materials USGS-37 and USGS -38; analytical precision better than ±0.4‰ was achieved. 37Cl/35Cl isotope ratio analysis in perchlorate during laboratory biodegradation experiment with microbial cultures enriched from the contaminated soil in Israel resulted in isotope enrichment factor ε37Cl = −13.3 ± 1‰, which falls in the range reported previously for perchlorate biodegradation by pure microbial cultures. The proposed analytical method may significantly simplify the procedure for isotope analysis of perchlorate which is currently applied in environmental studies.
Original languageEnglish
Pages (from-to)192-196
JournalChemosphere
Volume184
DOIs
StatePublished - Oct 2017

Keywords

  • Perchlorate
  • Chlorine isotope analysis
  • MC-ICPMS
  • Biodegradation

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