Complete intermolecular ligand crossover in hexacoordinate silicon dichelates-establishment of a ligand priority order

Shlomi Sergani, Inna Kalikhman, Shiri Yakubovich, Daniel Kost

Research output: Contribution to journalArticlepeer-review

14 Scopus citations

Abstract

Hexacoordinate silicon dichelates undergo three unique intermolecular chelate exchange reactions: complete ligand transfer from dichelates to trichlorosilanes, which is formally equivalent to interchange of monodentate ligands between dichelate and ZSiCl3, controlled by a ligand priority order; bidentate ligand interchange between dichelate and trimethylsilyl- hydrazide precursor; complete chelate crossover between different dichelates.

Original languageEnglish
Pages (from-to)5799-5802
Number of pages4
JournalOrganometallics
Volume26
Issue number24
DOIs
StatePublished - 19 Nov 2007

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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