Hexacoordinate silicon dichelates undergo three unique intermolecular chelate exchange reactions: complete ligand transfer from dichelates to trichlorosilanes, which is formally equivalent to interchange of monodentate ligands between dichelate and ZSiCl3, controlled by a ligand priority order; bidentate ligand interchange between dichelate and trimethylsilyl- hydrazide precursor; complete chelate crossover between different dichelates.
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry