Abstract
Hexacoordinate silicon dichelates undergo three unique intermolecular chelate exchange reactions: complete ligand transfer from dichelates to trichlorosilanes, which is formally equivalent to interchange of monodentate ligands between dichelate and ZSiCl3, controlled by a ligand priority order; bidentate ligand interchange between dichelate and trimethylsilyl- hydrazide precursor; complete chelate crossover between different dichelates.
Original language | English |
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Pages (from-to) | 5799-5802 |
Number of pages | 4 |
Journal | Organometallics |
Volume | 26 |
Issue number | 24 |
DOIs | |
State | Published - 19 Nov 2007 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry