Condensation of α-ethoxyacrolein with secondary amines

N. A. Keiko; A. Yu Rulev; I. D. Kalikhman; M. G. Voronkov

doi:10.1007/BF00956815

Condensation of α-ethoxyacrolein with secondary amines

N. A. Keiko, A. Yu Rulev, I. D. Kalikhman, M. G. Voronkov

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Abstract

Morpholine, piperidine, and dibutylamine undergo both 1,2 and 1,4 addition to α-ethoxyacrolein to form a mixture of 3,3- and 1,3-diamino-2-ethoxy-1-propenes. The N-formyl derivative of the starting amine is a side product. The reaction of α-ethoxyacrolein with diethylamine gives only splitting of the C-C bond and formation of N-formyldiethylamine.

Original language	English
Pages (from-to)	2419-2421
Number of pages	3
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	34
Issue number	11
DOIs	https://doi.org/10.1007/BF00956815
State	Published - 1 Nov 1985
Externally published	Yes

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General Chemistry

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title = "Condensation of α-ethoxyacrolein with secondary amines",

abstract = "Morpholine, piperidine, and dibutylamine undergo both 1,2 and 1,4 addition to α-ethoxyacrolein to form a mixture of 3,3- and 1,3-diamino-2-ethoxy-1-propenes. The N-formyl derivative of the starting amine is a side product. The reaction of α-ethoxyacrolein with diethylamine gives only splitting of the C-C bond and formation of N-formyldiethylamine.",

author = "Keiko, {N. A.} and Rulev, {A. Yu} and Kalikhman, {I. D.} and Voronkov, {M. G.}",

year = "1985",

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language = "English",

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journal = "Bulletin of the Academy of Sciences of the USSR Division of Chemical Science",

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T1 - Condensation of α-ethoxyacrolein with secondary amines

AU - Keiko, N. A.

AU - Rulev, A. Yu

AU - Kalikhman, I. D.

AU - Voronkov, M. G.

PY - 1985/11/1

Y1 - 1985/11/1

N2 - Morpholine, piperidine, and dibutylamine undergo both 1,2 and 1,4 addition to α-ethoxyacrolein to form a mixture of 3,3- and 1,3-diamino-2-ethoxy-1-propenes. The N-formyl derivative of the starting amine is a side product. The reaction of α-ethoxyacrolein with diethylamine gives only splitting of the C-C bond and formation of N-formyldiethylamine.

AB - Morpholine, piperidine, and dibutylamine undergo both 1,2 and 1,4 addition to α-ethoxyacrolein to form a mixture of 3,3- and 1,3-diamino-2-ethoxy-1-propenes. The N-formyl derivative of the starting amine is a side product. The reaction of α-ethoxyacrolein with diethylamine gives only splitting of the C-C bond and formation of N-formyldiethylamine.

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U2 - 10.1007/BF00956815

DO - 10.1007/BF00956815

M3 - Article

AN - SCOPUS:34250115471

SN - 0568-5230

VL - 34

SP - 2419

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JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 11

ER -

Condensation of α-ethoxyacrolein with secondary amines

Abstract

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