Conducting Olefin Metathesis Reactions in Air: Breaking the Paradigm

Stefano Guidone; Olivier Songis; Fady Nahra; Catherine S.J. Cazin

doi:10.1021/acscatal.5b00197

Conducting Olefin Metathesis Reactions in Air: Breaking the Paradigm

Stefano Guidone, Olivier Songis, Fady Nahra, Catherine S.J. Cazin

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

The first study of low catalyst loading olefin metathesis reactions in air is reported. TON values of up to 7000 were obtained using nondegassed solvents with commercially available precatalysts Caz-1, Hov-II, and Ind-II. The simple experimental conditions allow olefin metathesis reactions to be carried out on the benchtop using technical grade solvents in air. (Chemical Equation Presented).

Original language	English
Pages (from-to)	2697-2701
Number of pages	5
Journal	ACS Catalysis
Volume	5
Issue number	5
DOIs	https://doi.org/10.1021/acscatal.5b00197
State	Published - 1 May 2015
Externally published	Yes

Keywords

air
homogeneous catalysis
olefin metathesis
phosphite
ruthenium

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1021/acscatal.5b00197

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title = "Conducting Olefin Metathesis Reactions in Air: Breaking the Paradigm",

abstract = "The first study of low catalyst loading olefin metathesis reactions in air is reported. TON values of up to 7000 were obtained using nondegassed solvents with commercially available precatalysts Caz-1, Hov-II, and Ind-II. The simple experimental conditions allow olefin metathesis reactions to be carried out on the benchtop using technical grade solvents in air. (Chemical Equation Presented).",

keywords = "air, homogeneous catalysis, olefin metathesis, phosphite, ruthenium",

author = "Stefano Guidone and Olivier Songis and Fady Nahra and Cazin, {Catherine S.J.}",

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T1 - Conducting Olefin Metathesis Reactions in Air

T2 - Breaking the Paradigm

AU - Guidone, Stefano

AU - Songis, Olivier

AU - Nahra, Fady

AU - Cazin, Catherine S.J.

PY - 2015/5/1

Y1 - 2015/5/1

N2 - The first study of low catalyst loading olefin metathesis reactions in air is reported. TON values of up to 7000 were obtained using nondegassed solvents with commercially available precatalysts Caz-1, Hov-II, and Ind-II. The simple experimental conditions allow olefin metathesis reactions to be carried out on the benchtop using technical grade solvents in air. (Chemical Equation Presented).

AB - The first study of low catalyst loading olefin metathesis reactions in air is reported. TON values of up to 7000 were obtained using nondegassed solvents with commercially available precatalysts Caz-1, Hov-II, and Ind-II. The simple experimental conditions allow olefin metathesis reactions to be carried out on the benchtop using technical grade solvents in air. (Chemical Equation Presented).

KW - air

KW - homogeneous catalysis

KW - olefin metathesis

KW - phosphite

KW - ruthenium

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JF - ACS Catalysis

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ER -

Conducting Olefin Metathesis Reactions in Air: Breaking the Paradigm

Abstract

Keywords

ASJC Scopus subject areas

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