Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures

Mark V. Khenkin; Eugene A. Katz; Antonio Abate; Giorgio Bardizza; Joseph J. Berry; Christoph Brabec; Francesca Brunetti; Vladimir Bulović; Quinn Burlingame; Aldo Di Carlo; Rongrong Cheacharoen; Yi Bing Cheng; Alexander Colsmann; Stephane Cros; Konrad Domanski; Michał Dusza; Christopher J. Fell; Stephen R. Forrest; Yulia Galagan; Diego Di Girolamo; Michael Grätzel; Anders Hagfeldt; Elizabeth von Hauff; Harald Hoppe; Jeff Kettle; Hans Köbler; Marina S. Leite; Shengzhong (Frank) Liu; Yueh Lin Loo; Joseph M. Luther; Chang Qi Ma; Morten Madsen; Matthieu Manceau; Muriel Matheron; Michael McGehee; Rico Meitzner; Mohammad Khaja Nazeeruddin; Ana Flavia Nogueira; Çağla Odabaşı; Anna Osherov; Nam Gyu Park; Matthew O. Reese; Francesca De Rossi; Michael Saliba; Ulrich S. Schubert; Henry J. Snaith; Samuel D. Stranks; Wolfgang Tress; Pavel A. Troshin; Vida Turkovic; Sjoerd Veenstra; Iris Visoly-Fisher; Aron Walsh; Trystan Watson; Haibing Xie; Ramazan Yıldırım; Shaik Mohammed Zakeeruddin; Kai Zhu; Monica Lira-Cantu

doi:10.1038/s41560-019-0529-5

Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures

Mark V. Khenkin, Eugene A. Katz, Antonio Abate, Giorgio Bardizza, Joseph J. Berry, Christoph Brabec, Francesca Brunetti, Vladimir Bulović, Quinn Burlingame, Aldo Di Carlo, Rongrong Cheacharoen, Yi Bing Cheng, Alexander Colsmann, Stephane Cros, Konrad Domanski, Michał Dusza, Christopher J. Fell, Stephen R. Forrest, Yulia Galagan, Diego Di GirolamoMichael Grätzel, Anders Hagfeldt, Elizabeth von Hauff, Harald Hoppe, Jeff Kettle, Hans Köbler, Marina S. Leite, Shengzhong (Frank) Liu, Yueh Lin Loo, Joseph M. Luther, Chang Qi Ma, Morten Madsen, Matthieu Manceau, Muriel Matheron, Michael McGehee, Rico Meitzner, Mohammad Khaja Nazeeruddin, Ana Flavia Nogueira, Çağla Odabaşı, Anna Osherov, Nam Gyu Park, Matthew O. Reese, Francesca De Rossi, Michael Saliba, Ulrich S. Schubert, Henry J. Snaith, Samuel D. Stranks, Wolfgang Tress, Pavel A. Troshin, Vida Turkovic, Sjoerd Veenstra, Iris Visoly-Fisher, Aron Walsh, Trystan Watson, Haibing Xie, Ramazan Yıldırım, Shaik Mohammed Zakeeruddin, Kai Zhu, Monica Lira-Cantu

The Swiss Institute for Dryland Environmental and Energy Research

Research output: Contribution to journal › Article › peer-review

997 Scopus citations

Abstract

Improving the long-term stability of perovskite solar cells is critical to the deployment of this technology. Despite the great emphasis laid on stability-related investigations, publications lack consistency in experimental procedures and parameters reported. It is therefore challenging to reproduce and compare results and thereby develop a deep understanding of degradation mechanisms. Here, we report a consensus between researchers in the field on procedures for testing perovskite solar cell stability, which are based on the International Summit on Organic Photovoltaic Stability (ISOS) protocols. We propose additional procedures to account for properties specific to PSCs such as ion redistribution under electric fields, reversible degradation and to distinguish ambient-induced degradation from other stress factors. These protocols are not intended as a replacement of the existing qualification standards, but rather they aim to unify the stability assessment and to understand failure modes. Finally, we identify key procedural information which we suggest reporting in publications to improve reproducibility and enable large data set analysis.

Original language	English
Pages (from-to)	35-49
Number of pages	15
Journal	Nature Energy
Volume	5
Issue number	1
DOIs	https://doi.org/10.1038/s41560-019-0529-5
State	Published - 1 Jan 2020

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Renewable Energy, Sustainability and the Environment
Fuel Technology
Energy Engineering and Power Technology

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1038/s41560-019-0529-5

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Khenkin, M. V., Katz, E. A., Abate, A., Bardizza, G., Berry, J. J., Brabec, C., Brunetti, F., Bulović, V., Burlingame, Q., Di Carlo, A., Cheacharoen, R., Cheng, Y. B., Colsmann, A., Cros, S., Domanski, K., Dusza, M., Fell, C. J., Forrest, S. R., Galagan, Y., ... Lira-Cantu, M. (2020). Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures. Nature Energy, 5(1), 35-49. https://doi.org/10.1038/s41560-019-0529-5

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abstract = "Improving the long-term stability of perovskite solar cells is critical to the deployment of this technology. Despite the great emphasis laid on stability-related investigations, publications lack consistency in experimental procedures and parameters reported. It is therefore challenging to reproduce and compare results and thereby develop a deep understanding of degradation mechanisms. Here, we report a consensus between researchers in the field on procedures for testing perovskite solar cell stability, which are based on the International Summit on Organic Photovoltaic Stability (ISOS) protocols. We propose additional procedures to account for properties specific to PSCs such as ion redistribution under electric fields, reversible degradation and to distinguish ambient-induced degradation from other stress factors. These protocols are not intended as a replacement of the existing qualification standards, but rather they aim to unify the stability assessment and to understand failure modes. Finally, we identify key procedural information which we suggest reporting in publications to improve reproducibility and enable large data set analysis.",

author = "Khenkin, {Mark V.} and Katz, {Eugene A.} and Antonio Abate and Giorgio Bardizza and Berry, {Joseph J.} and Christoph Brabec and Francesca Brunetti and Vladimir Bulovi{\'c} and Quinn Burlingame and {Di Carlo}, Aldo and Rongrong Cheacharoen and Cheng, {Yi Bing} and Alexander Colsmann and Stephane Cros and Konrad Domanski and Micha{\l} Dusza and Fell, {Christopher J.} and Forrest, {Stephen R.} and Yulia Galagan and {Di Girolamo}, Diego and Michael Gr{\"a}tzel and Anders Hagfeldt and {von Hauff}, Elizabeth and Harald Hoppe and Jeff Kettle and Hans K{\"o}bler and Leite, {Marina S.} and Liu, {Shengzhong (Frank)} and Loo, {Yueh Lin} and Luther, {Joseph M.} and Ma, {Chang Qi} and Morten Madsen and Matthieu Manceau and Muriel Matheron and Michael McGehee and Rico Meitzner and Nazeeruddin, {Mohammad Khaja} and Nogueira, {Ana Flavia} and {\c C}ağla Odaba{\c s}ı and Anna Osherov and Park, {Nam Gyu} and Reese, {Matthew O.} and {De Rossi}, Francesca and Michael Saliba and Schubert, {Ulrich S.} and Snaith, {Henry J.} and Stranks, {Samuel D.} and Wolfgang Tress and Troshin, {Pavel A.} and Vida Turkovic and Sjoerd Veenstra and Iris Visoly-Fisher and Aron Walsh and Trystan Watson and Haibing Xie and Ramazan Yıldırım and Zakeeruddin, {Shaik Mohammed} and Kai Zhu and Monica Lira-Cantu",

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year = "2020",

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doi = "10.1038/s41560-019-0529-5",

language = "English",

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Khenkin, MV, Katz, EA, Abate, A, Bardizza, G, Berry, JJ, Brabec, C, Brunetti, F, Bulović, V, Burlingame, Q, Di Carlo, A, Cheacharoen, R, Cheng, YB, Colsmann, A, Cros, S, Domanski, K, Dusza, M, Fell, CJ, Forrest, SR, Galagan, Y, Di Girolamo, D, Grätzel, M, Hagfeldt, A, von Hauff, E, Hoppe, H, Kettle, J, Köbler, H, Leite, MS, Liu, S, Loo, YL, Luther, JM, Ma, CQ, Madsen, M, Manceau, M, Matheron, M, McGehee, M, Meitzner, R, Nazeeruddin, MK, Nogueira, AF, Odabaşı, Ç, Osherov, A, Park, NG, Reese, MO, De Rossi, F, Saliba, M, Schubert, US, Snaith, HJ, Stranks, SD, Tress, W, Troshin, PA, Turkovic, V, Veenstra, S, Visoly-Fisher, I, Walsh, A, Watson, T, Xie, H, Yıldırım, R, Zakeeruddin, SM, Zhu, K & Lira-Cantu, M 2020, 'Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures', Nature Energy, vol. 5, no. 1, pp. 35-49. https://doi.org/10.1038/s41560-019-0529-5

TY - JOUR

T1 - Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures

AU - Khenkin, Mark V.

AU - Katz, Eugene A.

AU - Abate, Antonio

AU - Bardizza, Giorgio

AU - Berry, Joseph J.

AU - Brabec, Christoph

AU - Brunetti, Francesca

AU - Bulović, Vladimir

AU - Burlingame, Quinn

AU - Di Carlo, Aldo

AU - Cheacharoen, Rongrong

AU - Cheng, Yi Bing

AU - Colsmann, Alexander

AU - Cros, Stephane

AU - Domanski, Konrad

AU - Dusza, Michał

AU - Fell, Christopher J.

AU - Forrest, Stephen R.

AU - Galagan, Yulia

AU - Di Girolamo, Diego

AU - Grätzel, Michael

AU - Hagfeldt, Anders

AU - von Hauff, Elizabeth

AU - Hoppe, Harald

AU - Kettle, Jeff

AU - Köbler, Hans

AU - Leite, Marina S.

AU - Liu, Shengzhong (Frank)

AU - Loo, Yueh Lin

AU - Luther, Joseph M.

AU - Ma, Chang Qi

AU - Madsen, Morten

AU - Manceau, Matthieu

AU - Matheron, Muriel

AU - McGehee, Michael

AU - Meitzner, Rico

AU - Nazeeruddin, Mohammad Khaja

AU - Nogueira, Ana Flavia

AU - Odabaşı, Çağla

AU - Osherov, Anna

AU - Park, Nam Gyu

AU - Reese, Matthew O.

AU - De Rossi, Francesca

AU - Saliba, Michael

AU - Schubert, Ulrich S.

AU - Snaith, Henry J.

AU - Stranks, Samuel D.

AU - Tress, Wolfgang

AU - Troshin, Pavel A.

AU - Turkovic, Vida

AU - Veenstra, Sjoerd

AU - Visoly-Fisher, Iris

AU - Walsh, Aron

AU - Watson, Trystan

AU - Xie, Haibing

AU - Yıldırım, Ramazan

AU - Zakeeruddin, Shaik Mohammed

AU - Zhu, Kai

AU - Lira-Cantu, Monica

PY - 2020/1/1

Y1 - 2020/1/1

N2 - Improving the long-term stability of perovskite solar cells is critical to the deployment of this technology. Despite the great emphasis laid on stability-related investigations, publications lack consistency in experimental procedures and parameters reported. It is therefore challenging to reproduce and compare results and thereby develop a deep understanding of degradation mechanisms. Here, we report a consensus between researchers in the field on procedures for testing perovskite solar cell stability, which are based on the International Summit on Organic Photovoltaic Stability (ISOS) protocols. We propose additional procedures to account for properties specific to PSCs such as ion redistribution under electric fields, reversible degradation and to distinguish ambient-induced degradation from other stress factors. These protocols are not intended as a replacement of the existing qualification standards, but rather they aim to unify the stability assessment and to understand failure modes. Finally, we identify key procedural information which we suggest reporting in publications to improve reproducibility and enable large data set analysis.

AB - Improving the long-term stability of perovskite solar cells is critical to the deployment of this technology. Despite the great emphasis laid on stability-related investigations, publications lack consistency in experimental procedures and parameters reported. It is therefore challenging to reproduce and compare results and thereby develop a deep understanding of degradation mechanisms. Here, we report a consensus between researchers in the field on procedures for testing perovskite solar cell stability, which are based on the International Summit on Organic Photovoltaic Stability (ISOS) protocols. We propose additional procedures to account for properties specific to PSCs such as ion redistribution under electric fields, reversible degradation and to distinguish ambient-induced degradation from other stress factors. These protocols are not intended as a replacement of the existing qualification standards, but rather they aim to unify the stability assessment and to understand failure modes. Finally, we identify key procedural information which we suggest reporting in publications to improve reproducibility and enable large data set analysis.

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U2 - 10.1038/s41560-019-0529-5

DO - 10.1038/s41560-019-0529-5

M3 - Article

AN - SCOPUS:85078324623

SN - 2058-7546

VL - 5

SP - 35

EP - 49

JO - Nature Energy

JF - Nature Energy

IS - 1

ER -

Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures

Abstract

ASJC Scopus subject areas

UN SDGs

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