Abstract
Efficient and low-cost electrocatalysts for the hydrogen evolution reaction are highly desired for future renewable energy systems. Described herein is the reduction of water to hydrogen using a metal-free carbon nitride electrocatalyst which operates in neutral and alkaline environments. An efficient, easy, and general method for growing ordered carbon nitride on different electrodes was developed. The metal-free catalyst demonstrates low overpotential values, which are comparable to those of non-noble metals, with reasonable current densities. The facile deposition method enables the fabrication of many electronic and photoelectronic devices based on carbon nitride for renewable energy applications. A scoff at non-nobles: The reduction of water to hydrogen using a metal-free carbon nitride (C3N 4) electrocatalyst in neutral and alkaline environments is demonstrated. An efficient, easy, and general method for growing ordered carbon nitride on different electrodes was developed. The metal-free catalyst demonstrates low overpotential values, which are comparable to non-noble metals, with reasonable current densities.
Original language | English |
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Pages (from-to) | 3654-3658 |
Number of pages | 5 |
Journal | Angewandte Chemie - International Edition |
Volume | 53 |
Issue number | 14 |
DOIs | |
State | Published - 1 Apr 2014 |
Externally published | Yes |
Keywords
- carbon nitride
- electrochemistry
- hydrogen
- supramolecular chemistry
- surface chemistry
ASJC Scopus subject areas
- Catalysis
- General Chemistry