Conversion of single crystalline PbI2 to CH3NH3PbI3: Structural relations and transformation dynamics

Thomas M. Brenner, Yevgeny Rakita, Yonatan Orr, Eugenia Klein, Ishay Feldman, Michael Elbaum, David Cahen, Gary Hodes

Research output: Contribution to journalArticlepeer-review

73 Scopus citations


The realization of high-quality optoelectronic properties in halide perovskite semiconductors through low-temperature, low energy processing is unprecedented. Understanding the unique aspects of the formation chemistry of these semiconductors is a critical step toward understanding the genesis of high quality material via simple preparation procedures. The toolbox of preparation procedures for halide perovskites grows rapidly. The prototypical reaction is that between lead iodide (PbI2) and methylammonium iodide (CH3NH3I, abbr. MAI) to form the perovskite CH3NH3PbI3 (MAPbI3), which we discuss in this work. We investigate the conversion of small, single-crystalline PbI2 crystallites to MAPbI3 by two commonly used synthesis processes: reaction with MAI in solution or as a vapor. The single crystal nature of the PbI2 precursor allows definitive conclusions to be made about the relationship between the precursors and the final product, illuminating previously unobserved aspects of the reaction process. From in situ photoluminescence microscopy, we find that the reaction in solution begins via isolated nucleation events followed by growth from the nuclei. We observe via X-ray diffraction and morphological characterization that there is a strong orientational and structural relationship between the final stage of the solution-reacted MAPbI3 product and the initial PbI2 crystallite. In all these measurements, we find that the reaction does not proceed below a certain MAI threshold concentration, which allows the first experimental determination of a free energy of formation for a widely used synthetic procedure of ∼0.1 eV. From these conclusions, we present a more detailed hypothesis about the reaction pathway than has yet been proposed: Our results suggest that the reaction in solution begins with a topotactic nucleation event followed by grain growth by dissolution-reconstruction. By similar techniques, we find the reaction via vapor phase produces material lacking a preferred orientation, suggesting the transformation is dominated by a deconstruction-reconstruction process due to the higher thermal energy involved. We also find that the crystal lattice structure of the vapor-reacted material is clearly different from that of the solution-phase reaction due to the temperature conditions of the synthesis.

Original languageEnglish
Pages (from-to)6501-6510
Number of pages10
JournalChemistry of Materials
Issue number18
StatePublished - 27 Sep 2016
Externally publishedYes

ASJC Scopus subject areas

  • General Chemistry
  • General Chemical Engineering
  • Materials Chemistry


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