Coordination competition-driven synthesis of triple-shell hollow α-Fe                         2                         O                         3                          microspheres for lithium ion batteries

Tingmei Zhang; Jianzhong Zheng; Zhiqiang Liang; Bo Zhao; Huajie Zeng; Wei Guo; Liang Zhao; Yinghui Sun; Ibrahim Abdulhalim; Lin Jiang

doi:10.1016/j.electacta.2019.03.127

Coordination competition-driven synthesis of triple-shell hollow α-Fe ₂ O ₃ microspheres for lithium ion batteries

Tingmei Zhang, Jianzhong Zheng, Zhiqiang Liang, Bo Zhao, Huajie Zeng, Wei Guo, Liang Zhao, Yinghui Sun, Ibrahim Abdulhalim, Lin Jiang

Unit of Photonics and Electro-Optics Engineering

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Multi-shell hollow structure metal oxide materials, with the larger surface area and short diffusion lengths, are very promising for lithium-ion battery application as anode materials. However, the production of multi-shelled hollow structure is relatively cumbersome, and it is difficult to fabricate multi component metal oxide hollow structures. Herein, we developed a new one-step hydrothermal method for synthesizing α-Fe ₂ O ₃ triple-shell hollow microspheres (TSHMs) by introducing urea as a coordination competitive agent. The triple-shell hollow structured α-Fe ₂ O ₃ accommodates large volume change and provides abundant active sites enable it as an ideal material for lithium ion battery applications. We have demonstrated the high specific capacity of 903.6 mA h g ⁻¹ at a current density of 500 mA g ⁻¹ even after 1000 cycles by using the α-Fe ₂ O ₃ TSHMs as anode material.

Original language	English
Pages (from-to)	151-158
Number of pages	8
Journal	Electrochimica Acta
Volume	306
DOIs	https://doi.org/10.1016/j.electacta.2019.03.127
State	Published - 20 May 2019

Keywords

Anode material
Hydrothermal method
Lithium ion batteries
Triple-shell hollow microspheres
α-Fe O

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.electacta.2019.03.127

Cite this

Zhang, T., Zheng, J., Liang, Z., Zhao, B., Zeng, H., Guo, W., Zhao, L., Sun, Y., Abdulhalim, I., & Jiang, L. (2019). Coordination competition-driven synthesis of triple-shell hollow α-Fe ₂ O ₃ microspheres for lithium ion batteries Electrochimica Acta, 306, 151-158. https://doi.org/10.1016/j.electacta.2019.03.127

Zhang, Tingmei ; Zheng, Jianzhong ; Liang, Zhiqiang ; Zhao, Bo ; Zeng, Huajie ; Guo, Wei ; Zhao, Liang ; Sun, Yinghui ; Abdulhalim, Ibrahim ; Jiang, Lin. / Coordination competition-driven synthesis of triple-shell hollow α-Fe ₂ O ₃ microspheres for lithium ion batteries In: Electrochimica Acta. 2019 ; Vol. 306. pp. 151-158.

@article{a9974e2ff7dd4a05b47838cf525243ef,

title = " Coordination competition-driven synthesis of triple-shell hollow α-Fe 2 O 3 microspheres for lithium ion batteries ",

abstract = " Multi-shell hollow structure metal oxide materials, with the larger surface area and short diffusion lengths, are very promising for lithium-ion battery application as anode materials. However, the production of multi-shelled hollow structure is relatively cumbersome, and it is difficult to fabricate multi component metal oxide hollow structures. Herein, we developed a new one-step hydrothermal method for synthesizing α-Fe 2 O 3 triple-shell hollow microspheres (TSHMs) by introducing urea as a coordination competitive agent. The triple-shell hollow structured α-Fe 2 O 3 accommodates large volume change and provides abundant active sites enable it as an ideal material for lithium ion battery applications. We have demonstrated the high specific capacity of 903.6 mA h g −1 at a current density of 500 mA g −1 even after 1000 cycles by using the α-Fe 2 O 3 TSHMs as anode material. ",

keywords = "Anode material, Hydrothermal method, Lithium ion batteries, Triple-shell hollow microspheres, α-Fe O",

author = "Tingmei Zhang and Jianzhong Zheng and Zhiqiang Liang and Bo Zhao and Huajie Zeng and Wei Guo and Liang Zhao and Yinghui Sun and Ibrahim Abdulhalim and Lin Jiang",

note = "Funding Information: This work was financially supported by National Key R&D Program of China (International Collaboration program) granted by Chinese Ministry of Science and Technology ( 2016YFE0129800 ) and the Israel Ministry of Science, Technology and Space . This is also a project supported by the National Natural Science Foundation of China ( 21822202 and 21373144 ) and the Natural Science Foundation of Jiangsu Province ( BK20150007 ). This is a project funded by 111 project , Joint International Research Laboratory of Carbon-Based Functional Materials and Devices , Collaborative Innovation Center of Suzhou Nano Science & Technology , and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) . Publisher Copyright: {\textcopyright} 2019 Elsevier Ltd",

year = "2019",

month = may,

day = "20",

doi = "10.1016/j.electacta.2019.03.127",

language = "English",

volume = "306",

pages = "151--158",

journal = "Electrochimica Acta",

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Zhang, T, Zheng, J, Liang, Z, Zhao, B, Zeng, H, Guo, W, Zhao, L, Sun, Y, Abdulhalim, I & Jiang, L 2019, ' Coordination competition-driven synthesis of triple-shell hollow α-Fe ₂ O ₃ microspheres for lithium ion batteries ', Electrochimica Acta, vol. 306, pp. 151-158. https://doi.org/10.1016/j.electacta.2019.03.127

Coordination competition-driven synthesis of triple-shell hollow α-Fe ₂ O ₃ microspheres for lithium ion batteries . / Zhang, Tingmei; Zheng, Jianzhong; Liang, Zhiqiang; Zhao, Bo; Zeng, Huajie; Guo, Wei; Zhao, Liang; Sun, Yinghui; Abdulhalim, Ibrahim; Jiang, Lin.

In: Electrochimica Acta, Vol. 306, 20.05.2019, p. 151-158.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Coordination competition-driven synthesis of triple-shell hollow α-Fe 2 O 3 microspheres for lithium ion batteries

AU - Zhang, Tingmei

AU - Zheng, Jianzhong

AU - Liang, Zhiqiang

AU - Zhao, Bo

AU - Zeng, Huajie

AU - Guo, Wei

AU - Zhao, Liang

AU - Sun, Yinghui

AU - Abdulhalim, Ibrahim

AU - Jiang, Lin

N1 - Funding Information: This work was financially supported by National Key R&D Program of China (International Collaboration program) granted by Chinese Ministry of Science and Technology ( 2016YFE0129800 ) and the Israel Ministry of Science, Technology and Space . This is also a project supported by the National Natural Science Foundation of China ( 21822202 and 21373144 ) and the Natural Science Foundation of Jiangsu Province ( BK20150007 ). This is a project funded by 111 project , Joint International Research Laboratory of Carbon-Based Functional Materials and Devices , Collaborative Innovation Center of Suzhou Nano Science & Technology , and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) . Publisher Copyright: © 2019 Elsevier Ltd

PY - 2019/5/20

Y1 - 2019/5/20

N2 - Multi-shell hollow structure metal oxide materials, with the larger surface area and short diffusion lengths, are very promising for lithium-ion battery application as anode materials. However, the production of multi-shelled hollow structure is relatively cumbersome, and it is difficult to fabricate multi component metal oxide hollow structures. Herein, we developed a new one-step hydrothermal method for synthesizing α-Fe 2 O 3 triple-shell hollow microspheres (TSHMs) by introducing urea as a coordination competitive agent. The triple-shell hollow structured α-Fe 2 O 3 accommodates large volume change and provides abundant active sites enable it as an ideal material for lithium ion battery applications. We have demonstrated the high specific capacity of 903.6 mA h g −1 at a current density of 500 mA g −1 even after 1000 cycles by using the α-Fe 2 O 3 TSHMs as anode material.

AB - Multi-shell hollow structure metal oxide materials, with the larger surface area and short diffusion lengths, are very promising for lithium-ion battery application as anode materials. However, the production of multi-shelled hollow structure is relatively cumbersome, and it is difficult to fabricate multi component metal oxide hollow structures. Herein, we developed a new one-step hydrothermal method for synthesizing α-Fe 2 O 3 triple-shell hollow microspheres (TSHMs) by introducing urea as a coordination competitive agent. The triple-shell hollow structured α-Fe 2 O 3 accommodates large volume change and provides abundant active sites enable it as an ideal material for lithium ion battery applications. We have demonstrated the high specific capacity of 903.6 mA h g −1 at a current density of 500 mA g −1 even after 1000 cycles by using the α-Fe 2 O 3 TSHMs as anode material.

KW - Anode material

KW - Hydrothermal method

KW - Lithium ion batteries

KW - Triple-shell hollow microspheres

KW - α-Fe O

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U2 - 10.1016/j.electacta.2019.03.127

DO - 10.1016/j.electacta.2019.03.127

M3 - Article

AN - SCOPUS:85063678584

VL - 306

SP - 151

EP - 158

JO - Electrochimica Acta

JF - Electrochimica Acta

SN - 0013-4686

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Zhang T, Zheng J, Liang Z, Zhao B, Zeng H, Guo W et al. Coordination competition-driven synthesis of triple-shell hollow α-Fe ₂ O ₃ microspheres for lithium ion batteries Electrochimica Acta. 2019 May 20;306:151-158. https://doi.org/10.1016/j.electacta.2019.03.127