TY - JOUR
T1 - Coordination complexes of copper(II) with herbicide-trichlorophenoxyacetate
T2 - Syntheses, characterization, single crystal X-ray structure and packing analyses of monomeric [Cu(γ-pic)3(2,4,5-trichlorophenoxyacetate)]·H2O, [trans-Cu(en)2(2,4,5-trichlorophenoxyacetate)2]·2H2O and dimeric [Cu2(H2tea)2(2,4,5-trichlorophenoxyacetate)2]·2(H2O)
AU - Sharma, Raj Pal
AU - Saini, Anju
AU - Kumar, Jitendra
AU - Kumar, Santosh
AU - Venugopalan, Paloth
AU - Ferretti, Valeria
N1 - Publisher Copyright:
© 2016 Elsevier B.V.
PY - 2017/1/1
Y1 - 2017/1/1
N2 - Three novel coordination complexes of copper(II) with 2,4,5-trichlorophenoxyacetate [Cu(γ-pic)3(L)2]·H2O 1, [trans-Cu(en)2(L)2]·2H2O 2 and [Cu2(H2tea)2(L)2]·2H2O 3, where L = 2,4,5-trichlorophenoxyacetate, γ-pic = γ-picoline, en = ethylenediamine, H2tea = monodeprotonated triethanolamine, were synthesized by addition of γ-picoline/ethylenediamine/triethanolamine, respectively, to the hydrated Cu(2,4,5-trichlorophenoxyacetate)2suspended in methanol-water (4:1, v/v). The newly synthesized complexes have been characterized by elemental analyses, spectroscopic techniques (UV–Vis and FT-IR), magnetic moment determination, molar conductance studies, TGA and single crystal X-ray diffraction method. The structure determination revealed neutral nature of complexes in all the three cases, with different coordination geometry around the copper(II) metal centre depending upon nature of the N- or N,O-donor ligands. Hydrogen bonding network i.e. O–H⋯O and C–H⋯O in complexes 1, 3 and N–H⋯O, and O–H⋯O in complex 2 stabilizes crystal lattice in copper(II) complexes besides other non-covalent interactions.
AB - Three novel coordination complexes of copper(II) with 2,4,5-trichlorophenoxyacetate [Cu(γ-pic)3(L)2]·H2O 1, [trans-Cu(en)2(L)2]·2H2O 2 and [Cu2(H2tea)2(L)2]·2H2O 3, where L = 2,4,5-trichlorophenoxyacetate, γ-pic = γ-picoline, en = ethylenediamine, H2tea = monodeprotonated triethanolamine, were synthesized by addition of γ-picoline/ethylenediamine/triethanolamine, respectively, to the hydrated Cu(2,4,5-trichlorophenoxyacetate)2suspended in methanol-water (4:1, v/v). The newly synthesized complexes have been characterized by elemental analyses, spectroscopic techniques (UV–Vis and FT-IR), magnetic moment determination, molar conductance studies, TGA and single crystal X-ray diffraction method. The structure determination revealed neutral nature of complexes in all the three cases, with different coordination geometry around the copper(II) metal centre depending upon nature of the N- or N,O-donor ligands. Hydrogen bonding network i.e. O–H⋯O and C–H⋯O in complexes 1, 3 and N–H⋯O, and O–H⋯O in complex 2 stabilizes crystal lattice in copper(II) complexes besides other non-covalent interactions.
KW - 2,4,5-Trichlorophenoxyacetate
KW - Copper(II) complex
KW - Ethylenediamine
KW - Triethanolamine
KW - X-ray crystallography
KW - γ-Picoline
UR - http://www.scopus.com/inward/record.url?scp=85006699744&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2016.12.008
DO - 10.1016/j.ica.2016.12.008
M3 - Article
AN - SCOPUS:85006699744
SN - 0020-1693
VL - 457
SP - 59
EP - 68
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
ER -