Abstract
A new simulation approach is presented for predicting boron concentrations in the product water of seawater reverse osmosis operations. The new (numerical) approach links traditional mass-transfer models (the solution-diffusion transport approach and the concentration polarization film-layer model) with full aqueous-phase thermodynamic species characterization, performed by chemical equilibrium software (PHREEQC), based on the Pitzer approach. The new approach results in a more accurate calculation of the boric acid (B(OH)3) molar fraction which develops close to the membrane wall, on the feed side, thereby improving the prediction accuracy of B(OH)3 permeation. Specifically, acknowledging that the pH value of the feed invariably changes as seawater brine progresses through the membranes' train, calculation of this pH change, as performed in the new approach, enables a more physically-accurate and better simulation of the boric acid fraction. The new approach is shown in the paper to result in a prediction that matches better empirical results obtained from the operation of a pilot-scale SWRO plant, as compared to the traditional approach.
Original language | English |
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Pages (from-to) | 87-92 |
Number of pages | 6 |
Journal | Desalination |
Volume | 310 |
DOIs | |
State | Published - 1 Feb 2013 |
Externally published | Yes |
Keywords
- Boron permeation
- Pitzer approach
- SWRO
- Simulation
- Solution diffusion
ASJC Scopus subject areas
- General Chemistry
- General Chemical Engineering
- General Materials Science
- Water Science and Technology
- Mechanical Engineering