Covalent binding of a nickel macrocyclic complex to a silica support: Towards an electron exchange column

Smadar Attia; Alexander Shames; Israel Zilbermann; Gil Goobes; Eric Maimon; Dan Meyerstein

doi:10.1039/c3dt51962g

Covalent binding of a nickel macrocyclic complex to a silica support: Towards an electron exchange column

Smadar Attia
, Alexander Shames
, Israel Zilbermann
, Gil Goobes
, Eric Maimon
, Dan Meyerstein

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Ni(ii)L², L² = 1-propyl-1,3,5,8,12- pentaazacyclotetradecane, was covalently bound to a silica support. This complex can be reversibly oxidized to the corresponding Ni(iii) complex. The latter complex is relatively long lived. Therefore electron exchange columns based on this material can be prepared.

Original language	English
Pages (from-to)	103-110
Number of pages	8
Journal	Dalton Transactions
Volume	43
Issue number	1
DOIs	https://doi.org/10.1039/c3dt51962g
State	Published - 7 Jan 2014

ASJC Scopus subject areas

Inorganic Chemistry

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title = "Covalent binding of a nickel macrocyclic complex to a silica support: Towards an electron exchange column",

abstract = "Ni(ii)L2, L2 = 1-propyl-1,3,5,8,12- pentaazacyclotetradecane, was covalently bound to a silica support. This complex can be reversibly oxidized to the corresponding Ni(iii) complex. The latter complex is relatively long lived. Therefore electron exchange columns based on this material can be prepared.",

author = "Smadar Attia and Alexander Shames and Israel Zilbermann and Gil Goobes and Eric Maimon and Dan Meyerstein",

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T2 - Towards an electron exchange column

AU - Attia, Smadar

AU - Shames, Alexander

AU - Zilbermann, Israel

AU - Goobes, Gil

AU - Maimon, Eric

AU - Meyerstein, Dan

PY - 2014/1/7

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N2 - Ni(ii)L2, L2 = 1-propyl-1,3,5,8,12- pentaazacyclotetradecane, was covalently bound to a silica support. This complex can be reversibly oxidized to the corresponding Ni(iii) complex. The latter complex is relatively long lived. Therefore electron exchange columns based on this material can be prepared.

AB - Ni(ii)L2, L2 = 1-propyl-1,3,5,8,12- pentaazacyclotetradecane, was covalently bound to a silica support. This complex can be reversibly oxidized to the corresponding Ni(iii) complex. The latter complex is relatively long lived. Therefore electron exchange columns based on this material can be prepared.

UR - https://www.scopus.com/pages/publications/84889647678

U2 - 10.1039/c3dt51962g

DO - 10.1039/c3dt51962g

M3 - Article

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AN - SCOPUS:84889647678

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EP - 110

JO - Dalton Transactions

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IS - 1

ER -

Covalent binding of a nickel macrocyclic complex to a silica support: Towards an electron exchange column

Abstract

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