CpFe(CO)2TePh as a ligand for organometallic dihalides Fe(CO)4I2, (p-Cymene)RuI2, and Me5C5RhI2: Synthesis and molecular structures

A. A. Pasynskii; I. V. Skabitskiy; Yu V. Torubaev; A. V. Pavlova; S. S. Shapovalov; O. G. Tikhonova; S. G. Sakharov

doi:10.1134/S1070328417010067

CpFe(CO)₂TePh as a ligand for organometallic dihalides Fe(CO)₄I₂, (p-Cymene)RuI₂, and Me₅C₅RhI₂: Synthesis and molecular structures

A. A. Pasynskii, I. V. Skabitskiy, Yu V. Torubaev, A. V. Pavlova, S. S. Shapovalov, O. G. Tikhonova, S. G. Sakharov

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

CpFe(CO)₂TePh (I) can substitute one carbonyl group in Fe(CO)₄I₂ providing Fe(CO)₃I₂(μ-TePh)Fe(CO)₂Cp (II) or play role of ligand to monomeric fragments [(p-Cymene)RuI₂] and [Сp*RhI₂] (p-Cymene = (η⁶-1-isopropyl-4-methylbenzene); Сp* = η⁵-pentamethylcyclopentadienyl) provides the complexes (p-Cymene)RuI₂(μ-TePh)Fe(CO)₂Cp (III) and Cp*RhCl₂(μ-TePh)Fe(CO)₂Cp (IV), respectively. The single-crystal X-ray diffraction of complexes II–IV (CIF files CCDC nos. 1038124 (II), 1038127 (III), 1038125 (IV)) revealed the shortening of М–Те bonds and the presence of intramolecular I…Te contacts.

Original language	English
Pages (from-to)	44-49
Number of pages	6
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	43
Issue number	1
DOIs	https://doi.org/10.1134/S1070328417010067
State	Published - 1 Jan 2017
Externally published	Yes

Keywords

X-ray diffraction
iron
mixed-metal complexes
organometallic compounds
rhodium
ruthenium
structure
tellurolate ligands

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

Access to Document

10.1134/S1070328417010067

Cite this

Pasynskii, A. A., Skabitskiy, I. V., Torubaev, Y. V., Pavlova, A. V., Shapovalov, S. S., Tikhonova, O. G., & Sakharov, S. G. (2017). CpFe(CO)₂TePh as a ligand for organometallic dihalides Fe(CO)₄I₂, (p-Cymene)RuI₂, and Me₅C₅RhI₂: Synthesis and molecular structures. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 43(1), 44-49. https://doi.org/10.1134/S1070328417010067

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title = "CpFe(CO)2TePh as a ligand for organometallic dihalides Fe(CO)4I2, (p-Cymene)RuI2, and Me5C5RhI2: Synthesis and molecular structures",

abstract = "CpFe(CO)2TePh (I) can substitute one carbonyl group in Fe(CO)4I2 providing Fe(CO)3I2(μ-TePh)Fe(CO)2Cp (II) or play role of ligand to monomeric fragments [(p-Cymene)RuI2] and [Сp*RhI2] (p-Cymene = (η6-1-isopropyl-4-methylbenzene); Сp* = η5-pentamethylcyclopentadienyl) provides the complexes (p-Cymene)RuI2(μ-TePh)Fe(CO)2Cp (III) and Cp*RhCl2(μ-TePh)Fe(CO)2Cp (IV), respectively. The single-crystal X-ray diffraction of complexes II–IV (CIF files CCDC nos. 1038124 (II), 1038127 (III), 1038125 (IV)) revealed the shortening of М–Те bonds and the presence of intramolecular I…Te contacts.",

keywords = "X-ray diffraction, iron, mixed-metal complexes, organometallic compounds, rhodium, ruthenium, structure, tellurolate ligands",

author = "Pasynskii, {A. A.} and Skabitskiy, {I. V.} and Torubaev, {Yu V.} and Pavlova, {A. V.} and Shapovalov, {S. S.} and Tikhonova, {O. G.} and Sakharov, {S. G.}",

note = "Publisher Copyright: {\textcopyright} 2017, Pleiades Publishing, Ltd.",

year = "2017",

month = jan,

day = "1",

doi = "10.1134/S1070328417010067",

language = "English",

volume = "43",

pages = "44--49",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

issn = "1070-3284",

publisher = "Pleiades Publishing",

number = "1",

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Pasynskii, AA, Skabitskiy, IV, Torubaev, YV, Pavlova, AV, Shapovalov, SS, Tikhonova, OG & Sakharov, SG 2017, 'CpFe(CO)₂TePh as a ligand for organometallic dihalides Fe(CO)₄I₂, (p-Cymene)RuI₂, and Me₅C₅RhI₂: Synthesis and molecular structures', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 43, no. 1, pp. 44-49. https://doi.org/10.1134/S1070328417010067

CpFe(CO)₂TePh as a ligand for organometallic dihalides Fe(CO)₄I₂, (p-Cymene)RuI₂, and Me₅C₅RhI₂: Synthesis and molecular structures. / Pasynskii, A. A.; Skabitskiy, I. V.; Torubaev, Yu V. et al.
In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 43, No. 1, 01.01.2017, p. 44-49.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - CpFe(CO)2TePh as a ligand for organometallic dihalides Fe(CO)4I2, (p-Cymene)RuI2, and Me5C5RhI2

T2 - Synthesis and molecular structures

AU - Pasynskii, A. A.

AU - Skabitskiy, I. V.

AU - Torubaev, Yu V.

AU - Pavlova, A. V.

AU - Shapovalov, S. S.

AU - Tikhonova, O. G.

AU - Sakharov, S. G.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - CpFe(CO)2TePh (I) can substitute one carbonyl group in Fe(CO)4I2 providing Fe(CO)3I2(μ-TePh)Fe(CO)2Cp (II) or play role of ligand to monomeric fragments [(p-Cymene)RuI2] and [Сp*RhI2] (p-Cymene = (η6-1-isopropyl-4-methylbenzene); Сp* = η5-pentamethylcyclopentadienyl) provides the complexes (p-Cymene)RuI2(μ-TePh)Fe(CO)2Cp (III) and Cp*RhCl2(μ-TePh)Fe(CO)2Cp (IV), respectively. The single-crystal X-ray diffraction of complexes II–IV (CIF files CCDC nos. 1038124 (II), 1038127 (III), 1038125 (IV)) revealed the shortening of М–Те bonds and the presence of intramolecular I…Te contacts.

AB - CpFe(CO)2TePh (I) can substitute one carbonyl group in Fe(CO)4I2 providing Fe(CO)3I2(μ-TePh)Fe(CO)2Cp (II) or play role of ligand to monomeric fragments [(p-Cymene)RuI2] and [Сp*RhI2] (p-Cymene = (η6-1-isopropyl-4-methylbenzene); Сp* = η5-pentamethylcyclopentadienyl) provides the complexes (p-Cymene)RuI2(μ-TePh)Fe(CO)2Cp (III) and Cp*RhCl2(μ-TePh)Fe(CO)2Cp (IV), respectively. The single-crystal X-ray diffraction of complexes II–IV (CIF files CCDC nos. 1038124 (II), 1038127 (III), 1038125 (IV)) revealed the shortening of М–Те bonds and the presence of intramolecular I…Te contacts.

KW - X-ray diffraction

KW - iron

KW - mixed-metal complexes

KW - organometallic compounds

KW - rhodium

KW - ruthenium

KW - structure

KW - tellurolate ligands

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U2 - 10.1134/S1070328417010067

DO - 10.1134/S1070328417010067

M3 - Article

AN - SCOPUS:85012975614

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JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

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