Cross-Dehydrogenative Coupling/Annulation of Arene Carboxylic Acids and Alkenes in Water with Ruthenium(II) Catalyst and Air

Anup Mandal; Bholanath Garai; Suman Dana; Ratnadeep Bera; Mahiuddin Baidya

doi:10.1002/asia.202001087

Cross-Dehydrogenative Coupling/Annulation of Arene Carboxylic Acids and Alkenes in Water with Ruthenium(II) Catalyst and Air

Anup Mandal, Bholanath Garai, Suman Dana, Ratnadeep Bera, Mahiuddin Baidya

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

A cross-dehydrogenative coupling of arene carboxylic acids with olefins is reported with ruthenium(II) catalyst employing air and water as green oxidant and solvent, respectively. It offers a robust synthesis of valuable phthalide molecules. A one-pot sequential strategy is also disclosed to access Heck-type products that are apparently difficult to make directly from arene carboxylic acids.

Original language	English
Pages (from-to)	4009-4013
Number of pages	5
Journal	Chemistry - An Asian Journal
Volume	15
Issue number	23
DOIs	https://doi.org/10.1002/asia.202001087
State	Published - 1 Dec 2020
Externally published	Yes

Keywords

Aromatic carboxylic acids
Cross-dehydrogenative coupling
C−H activation
Green synthesis
Ruthenium(II) catalysis

ASJC Scopus subject areas

Biochemistry
Organic Chemistry

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title = "Cross-Dehydrogenative Coupling/Annulation of Arene Carboxylic Acids and Alkenes in Water with Ruthenium(II) Catalyst and Air",

abstract = "A cross-dehydrogenative coupling of arene carboxylic acids with olefins is reported with ruthenium(II) catalyst employing air and water as green oxidant and solvent, respectively. It offers a robust synthesis of valuable phthalide molecules. A one-pot sequential strategy is also disclosed to access Heck-type products that are apparently difficult to make directly from arene carboxylic acids.",

keywords = "Aromatic carboxylic acids, Cross-dehydrogenative coupling, C−H activation, Green synthesis, Ruthenium(II) catalysis",

author = "Anup Mandal and Bholanath Garai and Suman Dana and Ratnadeep Bera and Mahiuddin Baidya",

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AU - Mandal, Anup

AU - Garai, Bholanath

AU - Dana, Suman

AU - Bera, Ratnadeep

AU - Baidya, Mahiuddin

PY - 2020/12/1

Y1 - 2020/12/1

N2 - A cross-dehydrogenative coupling of arene carboxylic acids with olefins is reported with ruthenium(II) catalyst employing air and water as green oxidant and solvent, respectively. It offers a robust synthesis of valuable phthalide molecules. A one-pot sequential strategy is also disclosed to access Heck-type products that are apparently difficult to make directly from arene carboxylic acids.

AB - A cross-dehydrogenative coupling of arene carboxylic acids with olefins is reported with ruthenium(II) catalyst employing air and water as green oxidant and solvent, respectively. It offers a robust synthesis of valuable phthalide molecules. A one-pot sequential strategy is also disclosed to access Heck-type products that are apparently difficult to make directly from arene carboxylic acids.

KW - Aromatic carboxylic acids

KW - Cross-dehydrogenative coupling

KW - C−H activation

KW - Green synthesis

KW - Ruthenium(II) catalysis

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Cross-Dehydrogenative Coupling/Annulation of Arene Carboxylic Acids and Alkenes in Water with Ruthenium(II) Catalyst and Air

Abstract

Keywords

ASJC Scopus subject areas

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