Cross-link-induced autophobicity in polymer melts: A re-entrant wetting transition

T. Kerle; R. Yerushalmi-Rozen; J. Klein

doi:10.1209/epl/i1997-00226-8

Cross-link-induced autophobicity in polymer melts: A re-entrant wetting transition

T. Kerle, R. Yerushalmi-Rozen, J. Klein

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40 Scopus citations

Abstract

We have investigated the wetting behaviour of a polymer melt on top of a cross-linked network of itself. For substrate films that were not cross-linked at all (or at very low cross-link densities) the melt completely wets the underlying layer. At intermediate cross-linking densities we observe dewetting, which we suggest is due to the brush-like surface of the network. At higher cross-linking densities the melt again completely wets the network, due, we believe, to increased roughening of the surface of the cross-linked substrate.

Original language	English
Pages (from-to)	207-212
Number of pages	6
Journal	EPL
Volume	38
Issue number	3
DOIs	https://doi.org/10.1209/epl/i1997-00226-8
State	Published - 20 Apr 1997
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy

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10.1209/epl/i1997-00226-8

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abstract = "We have investigated the wetting behaviour of a polymer melt on top of a cross-linked network of itself. For substrate films that were not cross-linked at all (or at very low cross-link densities) the melt completely wets the underlying layer. At intermediate cross-linking densities we observe dewetting, which we suggest is due to the brush-like surface of the network. At higher cross-linking densities the melt again completely wets the network, due, we believe, to increased roughening of the surface of the cross-linked substrate.",

author = "T. Kerle and R. Yerushalmi-Rozen and J. Klein",

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T2 - A re-entrant wetting transition

AU - Kerle, T.

AU - Yerushalmi-Rozen, R.

AU - Klein, J.

PY - 1997/4/20

Y1 - 1997/4/20

N2 - We have investigated the wetting behaviour of a polymer melt on top of a cross-linked network of itself. For substrate films that were not cross-linked at all (or at very low cross-link densities) the melt completely wets the underlying layer. At intermediate cross-linking densities we observe dewetting, which we suggest is due to the brush-like surface of the network. At higher cross-linking densities the melt again completely wets the network, due, we believe, to increased roughening of the surface of the cross-linked substrate.

AB - We have investigated the wetting behaviour of a polymer melt on top of a cross-linked network of itself. For substrate films that were not cross-linked at all (or at very low cross-link densities) the melt completely wets the underlying layer. At intermediate cross-linking densities we observe dewetting, which we suggest is due to the brush-like surface of the network. At higher cross-linking densities the melt again completely wets the network, due, we believe, to increased roughening of the surface of the cross-linked substrate.

UR - https://www.scopus.com/pages/publications/0031579771

U2 - 10.1209/epl/i1997-00226-8

DO - 10.1209/epl/i1997-00226-8

M3 - Article

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EP - 212

JO - EPL

JF - EPL

IS - 3

ER -

Cross-link-induced autophobicity in polymer melts: A re-entrant wetting transition

Abstract

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