Deca-heterosubstituted corannulenes

Alla Pogoreltsev; Ephrath Solel; Doron Pappo; Ehud Keinan

doi:10.1039/c2cc31801f

Deca-heterosubstituted corannulenes

Alla Pogoreltsev, Ephrath Solel, Doron Pappo, Ehud Keinan

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

The Cu(i)-catalyzed Ullmann condensation reaction between aliphatic alcohols and sym-pentachlorocorannulene provides a convenient entry to 1,3,5,7,9-pentaalkoxycorannulenes. The latter are easily converted to novel deca-heterosubstituted derivatives, such as 1,3,5,7,9-penta-X-2,4,6,8,10-penta-Y-corannulenes by electrophilic aromatic substitution.

Original language	English
Pages (from-to)	5425-5427
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	44
DOIs	https://doi.org/10.1039/c2cc31801f
State	Published - 7 May 2012

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "The Cu(i)-catalyzed Ullmann condensation reaction between aliphatic alcohols and sym-pentachlorocorannulene provides a convenient entry to 1,3,5,7,9-pentaalkoxycorannulenes. The latter are easily converted to novel deca-heterosubstituted derivatives, such as 1,3,5,7,9-penta-X-2,4,6,8,10-penta-Y-corannulenes by electrophilic aromatic substitution.",

author = "Alla Pogoreltsev and Ephrath Solel and Doron Pappo and Ehud Keinan",

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AU - Pogoreltsev, Alla

AU - Solel, Ephrath

AU - Pappo, Doron

AU - Keinan, Ehud

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Y1 - 2012/5/7

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AB - The Cu(i)-catalyzed Ullmann condensation reaction between aliphatic alcohols and sym-pentachlorocorannulene provides a convenient entry to 1,3,5,7,9-pentaalkoxycorannulenes. The latter are easily converted to novel deca-heterosubstituted derivatives, such as 1,3,5,7,9-penta-X-2,4,6,8,10-penta-Y-corannulenes by electrophilic aromatic substitution.

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Deca-heterosubstituted corannulenes

Abstract

ASJC Scopus subject areas

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