Defect-property correlations in garnet crystals. VI. The electrical conductivity, defect structure, and optical properties of luminescent calcium and cerium-doped yttrium aluminum garnet

S. R. Rotman; H. L. Tuller; C. Warde

doi:10.1063/1.351289

Defect-property correlations in garnet crystals. VI. The electrical conductivity, defect structure, and optical properties of luminescent calcium and cerium-doped yttrium aluminum garnet

S. R. Rotman, H. L. Tuller, C. Warde

School of Electrical and Computer Engineering

Research output: Contribution to journal › Article › peer-review

76 Scopus citations

Abstract

The electrical and optical properties of calcium and cerium-doped yttrium aluminum garnet (Ca,Ce:YAG) have been studied. Ca,Ce:YAG is a mixed ionic and electronic conductor with an ionic conductivity activation energy of 4.3 eV. Evidence of cluster formation with a consequent higher-than-expected activation energy is presented. The cerium normally enters the crystal as Ce⁺⁴, but it may be converted to Ce⁺³ under reducing atmospheres at elevated temperatures.

Original language	English
Pages (from-to)	1209-1214
Number of pages	6
Journal	Journal of Applied Physics
Volume	71
Issue number	3
DOIs	https://doi.org/10.1063/1.351289
State	Published - 1 Dec 1992

ASJC Scopus subject areas

General Physics and Astronomy

Access to Document

10.1063/1.351289

Cite this

@article{576b99fd64644757bf614da91ae3845e,

title = "Defect-property correlations in garnet crystals. VI. The electrical conductivity, defect structure, and optical properties of luminescent calcium and cerium-doped yttrium aluminum garnet",

abstract = "The electrical and optical properties of calcium and cerium-doped yttrium aluminum garnet (Ca,Ce:YAG) have been studied. Ca,Ce:YAG is a mixed ionic and electronic conductor with an ionic conductivity activation energy of 4.3 eV. Evidence of cluster formation with a consequent higher-than-expected activation energy is presented. The cerium normally enters the crystal as Ce+4, but it may be converted to Ce+3 under reducing atmospheres at elevated temperatures.",

author = "Rotman, {S. R.} and Tuller, {H. L.} and C. Warde",

year = "1992",

month = dec,

day = "1",

doi = "10.1063/1.351289",

language = "English",

volume = "71",

pages = "1209--1214",

journal = "Journal of Applied Physics",

issn = "0021-8979",

publisher = "American Institute of Physics",

number = "3",

}

Defect-property correlations in garnet crystals. VI. The electrical conductivity, defect structure, and optical properties of luminescent calcium and cerium-doped yttrium aluminum garnet. / Rotman, S. R.; Tuller, H. L.; Warde, C.
In: Journal of Applied Physics, Vol. 71, No. 3, 01.12.1992, p. 1209-1214.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Defect-property correlations in garnet crystals. VI. The electrical conductivity, defect structure, and optical properties of luminescent calcium and cerium-doped yttrium aluminum garnet

AU - Rotman, S. R.

AU - Tuller, H. L.

AU - Warde, C.

PY - 1992/12/1

Y1 - 1992/12/1

N2 - The electrical and optical properties of calcium and cerium-doped yttrium aluminum garnet (Ca,Ce:YAG) have been studied. Ca,Ce:YAG is a mixed ionic and electronic conductor with an ionic conductivity activation energy of 4.3 eV. Evidence of cluster formation with a consequent higher-than-expected activation energy is presented. The cerium normally enters the crystal as Ce+4, but it may be converted to Ce+3 under reducing atmospheres at elevated temperatures.

AB - The electrical and optical properties of calcium and cerium-doped yttrium aluminum garnet (Ca,Ce:YAG) have been studied. Ca,Ce:YAG is a mixed ionic and electronic conductor with an ionic conductivity activation energy of 4.3 eV. Evidence of cluster formation with a consequent higher-than-expected activation energy is presented. The cerium normally enters the crystal as Ce+4, but it may be converted to Ce+3 under reducing atmospheres at elevated temperatures.

UR - http://www.scopus.com/inward/record.url?scp=0003305816&partnerID=8YFLogxK

U2 - 10.1063/1.351289

DO - 10.1063/1.351289

M3 - Article

AN - SCOPUS:0003305816

SN - 0021-8979

VL - 71

SP - 1209

EP - 1214

JO - Journal of Applied Physics

JF - Journal of Applied Physics

IS - 3

ER -

Defect-property correlations in garnet crystals. VI. The electrical conductivity, defect structure, and optical properties of luminescent calcium and cerium-doped yttrium aluminum garnet

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this