Delocalization and exchange effects in high-nuclearity vanadium clusters

Dante Gatteschi; Boris S. Tsukerblat

doi:10.1080/00268979300101111

Delocalization and exchange effects in high-nuclearity vanadium clusters

Dante Gatteschi, Boris S. Tsukerblat

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

A model is worked out for the interpretation of the magnetic properties of polyoxovanadium clusters, containing both localized and delocalized vanadium(IV). The role of exchange and delocalization is worked out parametrically for two model systems containing four localized and two and four delocalized vanadium(IV) over eight sites respectively. The effect of vibronic coupling is also taken into account.

Original language	English
Pages (from-to)	121-143
Number of pages	23
Journal	Molecular Physics
Volume	79
Issue number	1
DOIs	https://doi.org/10.1080/00268979300101111
State	Published - 1 Jan 1993
Externally published	Yes

ASJC Scopus subject areas

Biophysics
Molecular Biology
Condensed Matter Physics
Physical and Theoretical Chemistry

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1080/00268979300101111

Cite this

@article{c19a39af7ea147e79a58e68f4368ce46,

title = "Delocalization and exchange effects in high-nuclearity vanadium clusters",

abstract = "A model is worked out for the interpretation of the magnetic properties of polyoxovanadium clusters, containing both localized and delocalized vanadium(IV). The role of exchange and delocalization is worked out parametrically for two model systems containing four localized and two and four delocalized vanadium(IV) over eight sites respectively. The effect of vibronic coupling is also taken into account.",

author = "Dante Gatteschi and Tsukerblat, {Boris S.}",

year = "1993",

month = jan,

day = "1",

doi = "10.1080/00268979300101111",

language = "English",

volume = "79",

pages = "121--143",

journal = "Molecular Physics",

issn = "0026-8976",

publisher = "Taylor and Francis Ltd.",

number = "1",

}

TY - JOUR

T1 - Delocalization and exchange effects in high-nuclearity vanadium clusters

AU - Gatteschi, Dante

AU - Tsukerblat, Boris S.

PY - 1993/1/1

Y1 - 1993/1/1

N2 - A model is worked out for the interpretation of the magnetic properties of polyoxovanadium clusters, containing both localized and delocalized vanadium(IV). The role of exchange and delocalization is worked out parametrically for two model systems containing four localized and two and four delocalized vanadium(IV) over eight sites respectively. The effect of vibronic coupling is also taken into account.

AB - A model is worked out for the interpretation of the magnetic properties of polyoxovanadium clusters, containing both localized and delocalized vanadium(IV). The role of exchange and delocalization is worked out parametrically for two model systems containing four localized and two and four delocalized vanadium(IV) over eight sites respectively. The effect of vibronic coupling is also taken into account.

UR - http://www.scopus.com/inward/record.url?scp=0005134930&partnerID=8YFLogxK

U2 - 10.1080/00268979300101111

DO - 10.1080/00268979300101111

M3 - Article

AN - SCOPUS:0005134930

SN - 0026-8976

VL - 79

SP - 121

EP - 143

JO - Molecular Physics

JF - Molecular Physics

IS - 1

ER -

Delocalization and exchange effects in high-nuclearity vanadium clusters

Abstract

ASJC Scopus subject areas

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this