Abstract
Densities of binary mixtures of 1,4-dioxane with either ethyl acrylate, or butyl acrylate, or methyl methacrylate, or styrene have been measured as a function of composition at T = 298.15 K and atmospheric pressure with an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess volumes were correlated with the Redlich-Kister equation and with a series of Legendre polynomials. The excess volumes are positive for the mixtures of 1,4-dioxane with methyl methacrylate and butyl acrylate and negative for the mixtures of 1,4-dioxane and styrene. The excess volumes for the system 1,4-dioxane and ethyl acrylate are negative for mole fractions x of 1,4-dioxane less than or equal to about 0.44 and positive at x greater than about 0.4498 and positive thereafter.
Original language | English |
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Pages (from-to) | 239-250 |
Number of pages | 12 |
Journal | Journal of Chemical Thermodynamics |
Volume | 35 |
Issue number | 2 |
DOIs | |
State | Published - 1 Jan 2003 |
Keywords
- 1,4-dioxane
- Acrylic esters
- Densities
- Excess volumes
- Monomers
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
- General Materials Science
- Physical and Theoretical Chemistry