Density, excess volume, of binary systems at diferent temperatures

O. Garcia, H. Soto, S. Hernández, R. Peralta, G. Cortez, J. Wisniak

Research output: Contribution to conferencePaperpeer-review

Abstract

Densities of the binary systems of dimethyl carbonate with butyl methacrylate, allyl methacrylate, styrene, and vinyl acetate were measured as a function of the composition at 293.15, 303.15. and 313.15 K and 1 atm using an Anton Paar DMA 5000 oscillating U-tube densimeter. The excess molar volumes were negative for the system dimethyl carbonate + vinyl acetate and positive for the three other binaries, and became more so as the temperature increased from at 293.15 to 313.15 K. The calculated excess molar volumes were correlated with the Redlich-Kister equation and with a series of Legendre polynomials. An explanation of the results is presented based on the FTIR spectra of several mixtures of the different systems. This is an abstract of a paper presented at the 8th World Congress of Chemical Engineering (Montréal, Quebec, Canada 8/23-27/2009).

Original languageEnglish
Pagesnopagegiven
StatePublished - 1 Dec 2009
Event8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering - Montreal, QC, Canada
Duration: 23 Aug 200927 Aug 2009

Conference

Conference8th World Congress of Chemical Engineering: Incorporating the 59th Canadian Chemical Engineering Conference and the 24th Interamerican Congress of Chemical Engineering
Country/TerritoryCanada
CityMontreal, QC
Period23/08/0927/08/09

ASJC Scopus subject areas

  • Biotechnology
  • Chemical Health and Safety
  • Process Chemistry and Technology
  • Renewable Energy, Sustainability and the Environment

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