Density, excess volumes, and partial volumes of the binary systems of ethenyl ethanoate + butanol, 2-butanol, 2-methyl-1-propanol, and 2-methyl-2-propanol at 298.15K

René D. Peralta; Ramiro Infante; Gladis Cortez; Arturo Cisneros; Jaime Wisniak

doi:10.1080/009864490923439

Density, excess volumes, and partial volumes of the binary systems of ethenyl ethanoate + butanol, 2-butanol, 2-methyl-1-propanol, and 2-methyl-2-propanol at 298.15K

René D. Peralta, Ramiro Infante, Gladis Cortez, Arturo Cisneros, Jaime Wisniak

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Densities of the binary systems of ethenyl ethanoate (vinyl acetate) with 1-butanol, 2-butanol (sec-butanol), 2-methyl-1-propanol (iso-butanol), and 2-methyl-2-propanol (tert-butanol) have been measured as a function of the composition, at 298.15 K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess volumes were correlated with the Redlich-Kister equation and with a series of Legendre polynomials. The excess volumes are positive for the four binaries and became larger as the alcohol becomes more branched.

Original language	English
Pages (from-to)	1684-1694
Number of pages	11
Journal	Chemical Engineering Communications
Volume	192
Issue number	10-12
DOIs	https://doi.org/10.1080/009864490923439
State	Published - 1 Oct 2005

Keywords

Butanols
Densities
Ethenyl ethanoate
Excess volumes

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1080/009864490923439

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title = "Density, excess volumes, and partial volumes of the binary systems of ethenyl ethanoate + butanol, 2-butanol, 2-methyl-1-propanol, and 2-methyl-2-propanol at 298.15K",

abstract = "Densities of the binary systems of ethenyl ethanoate (vinyl acetate) with 1-butanol, 2-butanol (sec-butanol), 2-methyl-1-propanol (iso-butanol), and 2-methyl-2-propanol (tert-butanol) have been measured as a function of the composition, at 298.15 K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess volumes were correlated with the Redlich-Kister equation and with a series of Legendre polynomials. The excess volumes are positive for the four binaries and became larger as the alcohol becomes more branched.",

keywords = "Butanols, Densities, Ethenyl ethanoate, Excess volumes",

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language = "English",

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Density, excess volumes, and partial volumes of the binary systems of ethenyl ethanoate + butanol, 2-butanol, 2-methyl-1-propanol, and 2-methyl-2-propanol at 298.15K. / Peralta, René D.; Infante, Ramiro; Cortez, Gladis et al.
In: Chemical Engineering Communications, Vol. 192, No. 10-12, 01.10.2005, p. 1684-1694.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Density, excess volumes, and partial volumes of the binary systems of ethenyl ethanoate + butanol, 2-butanol, 2-methyl-1-propanol, and 2-methyl-2-propanol at 298.15K

AU - Peralta, René D.

AU - Infante, Ramiro

AU - Cortez, Gladis

AU - Cisneros, Arturo

AU - Wisniak, Jaime

PY - 2005/10/1

Y1 - 2005/10/1

N2 - Densities of the binary systems of ethenyl ethanoate (vinyl acetate) with 1-butanol, 2-butanol (sec-butanol), 2-methyl-1-propanol (iso-butanol), and 2-methyl-2-propanol (tert-butanol) have been measured as a function of the composition, at 298.15 K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess volumes were correlated with the Redlich-Kister equation and with a series of Legendre polynomials. The excess volumes are positive for the four binaries and became larger as the alcohol becomes more branched.

AB - Densities of the binary systems of ethenyl ethanoate (vinyl acetate) with 1-butanol, 2-butanol (sec-butanol), 2-methyl-1-propanol (iso-butanol), and 2-methyl-2-propanol (tert-butanol) have been measured as a function of the composition, at 298.15 K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess volumes were correlated with the Redlich-Kister equation and with a series of Legendre polynomials. The excess volumes are positive for the four binaries and became larger as the alcohol becomes more branched.

KW - Butanols

KW - Densities

KW - Ethenyl ethanoate

KW - Excess volumes

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SN - 0098-6445

VL - 192

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JO - Chemical Engineering Communications

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ER -

Density, excess volumes, and partial volumes of the binary systems of ethenyl ethanoate + butanol, 2-butanol, 2-methyl-1-propanol, and 2-methyl-2-propanol at 298.15K

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

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