Diffusion of sea water ions-I. Diffusion of sea water into a dilute solution

S. Ben-Yaakov

doi:10.1016/0016-7037(72)90069-5

Diffusion of sea water ions-I. Diffusion of sea water into a dilute solution

S. Ben-Yaakov

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

Derivations of Vinograd and McBain (1941) were applied to explain ionic diffusion out of sea water and into dilute solution. Models so constructed were found to be compatible with experimental data obtained from Cl^-, K⁺, Mg²⁺ and Ca²⁺ diffusion studies. The present investigation suggests that ionic interaction-resulting from the electroneutrality requirement-may extensively modify fluxes of diffusing ions and may also affect the relative distribution of both migrating and non-migrating ions. It is suggested that a change in the ratio ion Cl in interstitial waters of marine sediments does not necessarily imply that the ion is involved in a chemical reaction or that it migrates.

Original language	English
Pages (from-to)	1395-1406
Number of pages	12
Journal	Geochimica et Cosmochimica Acta
Volume	36
Issue number	12
DOIs	https://doi.org/10.1016/0016-7037(72)90069-5
State	Published - 1 Jan 1972
Externally published	Yes

ASJC Scopus subject areas

Geochemistry and Petrology

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10.1016/0016-7037(72)90069-5

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title = "Diffusion of sea water ions-I. Diffusion of sea water into a dilute solution",

abstract = "Derivations of Vinograd and McBain (1941) were applied to explain ionic diffusion out of sea water and into dilute solution. Models so constructed were found to be compatible with experimental data obtained from Cl-, K+, Mg2+ and Ca2+ diffusion studies. The present investigation suggests that ionic interaction-resulting from the electroneutrality requirement-may extensively modify fluxes of diffusing ions and may also affect the relative distribution of both migrating and non-migrating ions. It is suggested that a change in the ratio ion Cl in interstitial waters of marine sediments does not necessarily imply that the ion is involved in a chemical reaction or that it migrates.",

author = "S. Ben-Yaakov",

note = "Funding Information: AcLvwwZedgementgI wish to thank Professor I. R. KAPLAN for critically reading the manuscript, ED RUTH for aesistance in preparing the experimental set-up, and CERIETYS ANDBOIW for aeeietancei n the experimental and computational phases of the research. This study was supported by an AEC grant, AT(04-3)-34 P.A. 178.",

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T1 - Diffusion of sea water ions-I. Diffusion of sea water into a dilute solution

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N1 - Funding Information: AcLvwwZedgementgI wish to thank Professor I. R. KAPLAN for critically reading the manuscript, ED RUTH for aesistance in preparing the experimental set-up, and CERIETYS ANDBOIW for aeeietancei n the experimental and computational phases of the research. This study was supported by an AEC grant, AT(04-3)-34 P.A. 178.

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N2 - Derivations of Vinograd and McBain (1941) were applied to explain ionic diffusion out of sea water and into dilute solution. Models so constructed were found to be compatible with experimental data obtained from Cl-, K+, Mg2+ and Ca2+ diffusion studies. The present investigation suggests that ionic interaction-resulting from the electroneutrality requirement-may extensively modify fluxes of diffusing ions and may also affect the relative distribution of both migrating and non-migrating ions. It is suggested that a change in the ratio ion Cl in interstitial waters of marine sediments does not necessarily imply that the ion is involved in a chemical reaction or that it migrates.

AB - Derivations of Vinograd and McBain (1941) were applied to explain ionic diffusion out of sea water and into dilute solution. Models so constructed were found to be compatible with experimental data obtained from Cl-, K+, Mg2+ and Ca2+ diffusion studies. The present investigation suggests that ionic interaction-resulting from the electroneutrality requirement-may extensively modify fluxes of diffusing ions and may also affect the relative distribution of both migrating and non-migrating ions. It is suggested that a change in the ratio ion Cl in interstitial waters of marine sediments does not necessarily imply that the ion is involved in a chemical reaction or that it migrates.

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JO - Geochimica et Cosmochimica Acta

JF - Geochimica et Cosmochimica Acta

IS - 12

ER -

Diffusion of sea water ions-I. Diffusion of sea water into a dilute solution

Abstract

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