Dilute aqueous solutions with formate ions: A conductometric study

Matjaž Bončina; Alexander Apelblat; Marija Bešter-Rogač

doi:10.1021/je900903w

Dilute aqueous solutions with formate ions: A conductometric study

Matjaž Bončina, Alexander Apelblat, Marija Bešter-Rogač

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Molar conductivities, Λ, of dilute aqueous solutions (c = (≈3·10^-4 to ≈5·10^-3) mol·dm^-3) of sodium formate, potassium formate, and formic acid in the temperature range T = (278.15 to 313.15) K are reported. The experimental data are examined by applying the Quint-Viallard conductivity equations and the Debye-Hückel equations for activity coefficients. Limiting conductivities of formate anion in the investigated temperature range were obtained from the data for salts, and then the dissociation constants for formic acid were estimated. Results were compared with the available literature data.

Original language	English
Pages (from-to)	1951-1957
Number of pages	7
Journal	Journal of Chemical and Engineering Data
Volume	55
Issue number	5
DOIs	https://doi.org/10.1021/je900903w
State	Published - 13 May 2010

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

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title = "Dilute aqueous solutions with formate ions: A conductometric study",

abstract = "Molar conductivities, Λ, of dilute aqueous solutions (c = (≈3·10-4 to ≈5·10-3) mol·dm-3) of sodium formate, potassium formate, and formic acid in the temperature range T = (278.15 to 313.15) K are reported. The experimental data are examined by applying the Quint-Viallard conductivity equations and the Debye-H{\"u}ckel equations for activity coefficients. Limiting conductivities of formate anion in the investigated temperature range were obtained from the data for salts, and then the dissociation constants for formic acid were estimated. Results were compared with the available literature data.",

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T2 - A conductometric study

AU - Bončina, Matjaž

AU - Apelblat, Alexander

AU - Bešter-Rogač, Marija

PY - 2010/5/13

Y1 - 2010/5/13

N2 - Molar conductivities, Λ, of dilute aqueous solutions (c = (≈3·10-4 to ≈5·10-3) mol·dm-3) of sodium formate, potassium formate, and formic acid in the temperature range T = (278.15 to 313.15) K are reported. The experimental data are examined by applying the Quint-Viallard conductivity equations and the Debye-Hückel equations for activity coefficients. Limiting conductivities of formate anion in the investigated temperature range were obtained from the data for salts, and then the dissociation constants for formic acid were estimated. Results were compared with the available literature data.

AB - Molar conductivities, Λ, of dilute aqueous solutions (c = (≈3·10-4 to ≈5·10-3) mol·dm-3) of sodium formate, potassium formate, and formic acid in the temperature range T = (278.15 to 313.15) K are reported. The experimental data are examined by applying the Quint-Viallard conductivity equations and the Debye-Hückel equations for activity coefficients. Limiting conductivities of formate anion in the investigated temperature range were obtained from the data for salts, and then the dissociation constants for formic acid were estimated. Results were compared with the available literature data.

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IS - 5

ER -

Dilute aqueous solutions with formate ions: A conductometric study

Abstract

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