Dimer and trimer formation in dense gaseous argon: A MD study

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Abstract

Formation and dissociation rates of dimers and trimers in relatively dense ((0.61-1.21) x 1021 atoms/cm3) argon at 100-140 K were studied by MD simulation. Rate constants and equilibrium constants were evaluated, and their magnitudes and behavior agreed with previous values and predictions where available. The effects of local densities on the kinetics are discussed.

Original languageEnglish
Pages (from-to)3367-3370
Number of pages4
JournalJournal of Physical Chemistry A
Volume101
Issue number18
DOIs
StatePublished - 1 May 1997

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