Abstract
An X-ray study of chloro[1-{1,1-dimethyl-2-(4′methoxybenzoyl)hydrazonium} methyl]dimethylsilane (I) has been carried out (R = 0.035 for 2800 reflections). The Si atom, which has a trigonal-bipyramidal [4 + 1] coordination with the O and Cl atoms in axial positions (Si-O 1.788(1) Å, SiCl 2.624(1) Å, is markedly displaced from the equatorial plane towards the oxygen atom (ΔSi 0.178 Å), which confirms that there is a coordinate bond between the silicon atom and chloride ion.
Original language | English |
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Pages (from-to) | 23-30 |
Number of pages | 8 |
Journal | Journal of Organometallic Chemistry |
Volume | 356 |
Issue number | 1 |
DOIs | |
State | Published - 15 Nov 1988 |
Externally published | Yes |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry