Direct observation of power-law behavior in the asymptotic relaxation to equilibrium of a reversible bimolecular reaction

Dina Pines; Ehud Pines

doi:10.1063/1.1379572

Direct observation of power-law behavior in the asymptotic relaxation to equilibrium of a reversible bimolecular reaction

Dina Pines, Ehud Pines

Department of Chemistry

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38 Scopus citations

Abstract

The power-law relaxation to equlibrium of the diffusion influenced reversible reaction was reported. After the photoinitiation of the reaction, results confirmed t^-3/2 decay law relaxation of AB population. The value of concentration factor, β, was reported as 3. This was in agreement to the theoretical predictions.

Original language	English
Pages (from-to)	951-953
Number of pages	3
Journal	Journal of Chemical Physics
Volume	115
Issue number	2
DOIs	https://doi.org/10.1063/1.1379572
State	Published - 8 Jul 2001

ASJC Scopus subject areas

Physics and Astronomy (all)
Physical and Theoretical Chemistry

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title = "Direct observation of power-law behavior in the asymptotic relaxation to equilibrium of a reversible bimolecular reaction",

abstract = "The power-law relaxation to equlibrium of the diffusion influenced reversible reaction was reported. After the photoinitiation of the reaction, results confirmed t-3/2 decay law relaxation of AB population. The value of concentration factor, β, was reported as 3. This was in agreement to the theoretical predictions.",

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AB - The power-law relaxation to equlibrium of the diffusion influenced reversible reaction was reported. After the photoinitiation of the reaction, results confirmed t-3/2 decay law relaxation of AB population. The value of concentration factor, β, was reported as 3. This was in agreement to the theoretical predictions.

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Direct observation of power-law behavior in the asymptotic relaxation to equilibrium of a reversible bimolecular reaction

Abstract

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