Direct observation of power-law behavior in the asymptotic relaxation to equilibrium of a reversible bimolecular reaction

Dina Pines; Ehud Pines

doi:10.1063/1.1379572

Direct observation of power-law behavior in the asymptotic relaxation to equilibrium of a reversible bimolecular reaction

Dina Pines, Ehud Pines

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

The power-law relaxation to equlibrium of the diffusion influenced reversible reaction was reported. After the photoinitiation of the reaction, results confirmed t^-3/2 decay law relaxation of AB population. The value of concentration factor, β, was reported as 3. This was in agreement to the theoretical predictions.

Original language	English
Pages (from-to)	951-953
Number of pages	3
Journal	Journal of Chemical Physics
Volume	115
Issue number	2
DOIs	https://doi.org/10.1063/1.1379572
State	Published - 8 Jul 2001

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.1379572

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title = "Direct observation of power-law behavior in the asymptotic relaxation to equilibrium of a reversible bimolecular reaction",

abstract = "The power-law relaxation to equlibrium of the diffusion influenced reversible reaction was reported. After the photoinitiation of the reaction, results confirmed t-3/2 decay law relaxation of AB population. The value of concentration factor, β, was reported as 3. This was in agreement to the theoretical predictions.",

author = "Dina Pines and Ehud Pines",

year = "2001",

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T1 - Direct observation of power-law behavior in the asymptotic relaxation to equilibrium of a reversible bimolecular reaction

AU - Pines, Dina

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N2 - The power-law relaxation to equlibrium of the diffusion influenced reversible reaction was reported. After the photoinitiation of the reaction, results confirmed t-3/2 decay law relaxation of AB population. The value of concentration factor, β, was reported as 3. This was in agreement to the theoretical predictions.

AB - The power-law relaxation to equlibrium of the diffusion influenced reversible reaction was reported. After the photoinitiation of the reaction, results confirmed t-3/2 decay law relaxation of AB population. The value of concentration factor, β, was reported as 3. This was in agreement to the theoretical predictions.

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DO - 10.1063/1.1379572

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Direct observation of power-law behavior in the asymptotic relaxation to equilibrium of a reversible bimolecular reaction

Abstract

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