Directional photodissociation dynamics of alkyl nitrites and nitrosamines at 250 and 350 nm

E. Radian, D. Schwarz-Lavi, R. Lavi, I. Bar, S. Rosenwaks

Research output: Contribution to journalArticlepeer-review

Abstract

The geometry and symmetry of the first two excited singlet states, S1 and S2, of tert°butyl nitrite (TBN) and dimethylnitrosamine (DMN) were studied using laser induced polarization spectroscopy at 250 and 350 nm. The scalar and directional properties of the NO fragment illustrate the differences between S1 and S2 and between TBN and DMN dissociation dynamics.
Original languageEnglish GB
Pages (from-to)602-604
JournalAIP Conference Proceedings
Volume172
DOIs
StatePublished - 1 Oct 1988
Externally publishedYes

Keywords

  • Diffuse spectra
  • predissociation photodissociation

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