Directional photodissociation dynamics of alkyl nitrites and nitrosamines at 250 and 350 nm

E. Radian; D. Schwarz-Lavi; R. Lavi; I. Bar; S. Rosenwaks

doi:10.1063/1.37428

Directional photodissociation dynamics of alkyl nitrites and nitrosamines at 250 and 350 nm

E. Radian
, D. Schwarz-Lavi
, R. Lavi
, I. Bar
, S. Rosenwaks

Department of Physics

Research output: Contribution to journal › Article › peer-review

Abstract

The geometry and symmetry of the first two excited singlet states, S1 and S2, of tert°butyl nitrite (TBN) and dimethylnitrosamine (DMN) were studied using laser induced polarization spectroscopy at 250 and 350 nm. The scalar and directional properties of the NO fragment illustrate the differences between S1 and S2 and between TBN and DMN dissociation dynamics.

Original language	English
Pages (from-to)	602-604
Journal	AIP Conference Proceedings
Volume	172
Issue number	1
DOIs	https://doi.org/10.1063/1.37428
State	Published - 1 Oct 1988

Keywords

Diffuse spectra
predissociation photodissociation

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10.1063/1.37428

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title = "Directional photodissociation dynamics of alkyl nitrites and nitrosamines at 250 and 350 nm",

abstract = "The geometry and symmetry of the first two excited singlet states, S1 and S2, of tert°butyl nitrite (TBN) and dimethylnitrosamine (DMN) were studied using laser induced polarization spectroscopy at 250 and 350 nm. The scalar and directional properties of the NO fragment illustrate the differences between S1 and S2 and between TBN and DMN dissociation dynamics.",

keywords = "Diffuse spectra, predissociation photodissociation",

author = "E. Radian and D. Schwarz-Lavi and R. Lavi and I. Bar and S. Rosenwaks",

year = "1988",

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doi = "10.1063/1.37428",

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TY - JOUR

T1 - Directional photodissociation dynamics of alkyl nitrites and nitrosamines at 250 and 350 nm

AU - Radian, E.

AU - Schwarz-Lavi, D.

AU - Lavi, R.

AU - Bar, I.

AU - Rosenwaks, S.

PY - 1988/10/1

Y1 - 1988/10/1

N2 - The geometry and symmetry of the first two excited singlet states, S1 and S2, of tert°butyl nitrite (TBN) and dimethylnitrosamine (DMN) were studied using laser induced polarization spectroscopy at 250 and 350 nm. The scalar and directional properties of the NO fragment illustrate the differences between S1 and S2 and between TBN and DMN dissociation dynamics.

AB - The geometry and symmetry of the first two excited singlet states, S1 and S2, of tert°butyl nitrite (TBN) and dimethylnitrosamine (DMN) were studied using laser induced polarization spectroscopy at 250 and 350 nm. The scalar and directional properties of the NO fragment illustrate the differences between S1 and S2 and between TBN and DMN dissociation dynamics.

KW - Diffuse spectra

KW - predissociation photodissociation

U2 - 10.1063/1.37428

DO - 10.1063/1.37428

M3 - Article

SN - 0094-243X

VL - 172

SP - 602

EP - 604

JO - AIP Conference Proceedings

JF - AIP Conference Proceedings

IS - 1

ER -

Directional photodissociation dynamics of alkyl nitrites and nitrosamines at 250 and 350 nm

Abstract

Keywords

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