Dissociation of diatomic molecules into atoms with non-vanishing electronic angular momentum. physical motivation for theory

Yehuda B. Band; Karl F. Freed; Donald J. Kouri

doi:10.1016/0009-2614(81)80194-7

Dissociation of diatomic molecules into atoms with non-vanishing electronic angular momentum. physical motivation for theory

Yehuda B. Band, Karl F. Freed, Donald J. Kouri

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

Non-vanishing fragment electronic angular momentum implies the existence of non-adiabatic interactions between adiabatic moleular electronic states that become degenerate at large internuclear separations Our generalized theory of photodissociation is used to illustrate how cross sections and angular distributions for individual fine structure levels can be used to probe the presence ot non-adiabatic contributions to photodissociation.

Original language	English
Pages (from-to)	233-237
Number of pages	5
Journal	Chemical Physics Letters
Volume	79
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(81)80194-7
State	Published - 15 Apr 1981

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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title = "Dissociation of diatomic molecules into atoms with non-vanishing electronic angular momentum. physical motivation for theory",

abstract = "Non-vanishing fragment electronic angular momentum implies the existence of non-adiabatic interactions between adiabatic moleular electronic states that become degenerate at large internuclear separations Our generalized theory of photodissociation is used to illustrate how cross sections and angular distributions for individual fine structure levels can be used to probe the presence ot non-adiabatic contributions to photodissociation.",

author = "Band, {Yehuda B.} and Freed, {Karl F.} and Kouri, {Donald J.}",

note = "Funding Information: * Research supported IJI part by NSF CHE 80-23456 Funding Information: * Research supported III part by NSF CHE 7949098",

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T1 - Dissociation of diatomic molecules into atoms with non-vanishing electronic angular momentum. physical motivation for theory

AU - Band, Yehuda B.

AU - Freed, Karl F.

AU - Kouri, Donald J.

N1 - Funding Information: * Research supported IJI part by NSF CHE 80-23456 Funding Information: * Research supported III part by NSF CHE 7949098

PY - 1981/4/15

Y1 - 1981/4/15

N2 - Non-vanishing fragment electronic angular momentum implies the existence of non-adiabatic interactions between adiabatic moleular electronic states that become degenerate at large internuclear separations Our generalized theory of photodissociation is used to illustrate how cross sections and angular distributions for individual fine structure levels can be used to probe the presence ot non-adiabatic contributions to photodissociation.

AB - Non-vanishing fragment electronic angular momentum implies the existence of non-adiabatic interactions between adiabatic moleular electronic states that become degenerate at large internuclear separations Our generalized theory of photodissociation is used to illustrate how cross sections and angular distributions for individual fine structure levels can be used to probe the presence ot non-adiabatic contributions to photodissociation.

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DO - 10.1016/0009-2614(81)80194-7

M3 - Article

AN - SCOPUS:4243352177

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VL - 79

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JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 2

ER -

Dissociation of diatomic molecules into atoms with non-vanishing electronic angular momentum. physical motivation for theory

Abstract

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