Divinyl sulfoxide II. Vinylation and vinylsulfinylation of triorganylsilylalkanethiols by divinyl sulfoxide

M. G. Voronkov; N. N. Vlasova; F. P. Kletsko; N. K. Gusarova; G. G. Efremova; M. V. Sigalov; V. V. Keiko; S. B. Leonov; S. V. Amosova; B. A. Trofimov

doi:10.1007/BF00955301

Divinyl sulfoxide II. Vinylation and vinylsulfinylation of triorganylsilylalkanethiols by divinyl sulfoxide

M. G. Voronkov, N. N. Vlasova, F. P. Kletsko, N. K. Gusarova, G. G. Efremova, M. V. Sigalov, V. V. Keiko, S. B. Leonov, S. V. Amosova, B. A. Trofimov

Research output: Contribution to journal › Article › peer-review

Abstract

1. The nucleophilic addition reaction of triorganylsilylalkanethiols to divinyl sulfoxide leads to the formation of vinyl β-(triorganylsilylalkylthio)ethyl sulfoxides. The latter, as the result of thermal dissociation are transformed into vinyl triorganylsilylalkyl sulfides (the indirect vinylation reaction). 2. The nucleophilic reaction of triorganylsilylalkanethiols with divinyl sulfoxide is accompanied by a side oxidation- reduction process and a thiylation reaction, leading to the formation of vinyl β-(triorganylsilylalkylthio)ethyl sulfides, 1,1-bis(triorganylsilylalkylthio) ethanes and vinyl triorganylsilylalkyl disulfides.

Original language	English
Pages (from-to)	864-867
Number of pages	4
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	30
Issue number	5
DOIs	https://doi.org/10.1007/BF00955301
State	Published - 1 Jan 1981
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1007/BF00955301

Cite this

Voronkov, M. G., Vlasova, N. N., Kletsko, F. P., Gusarova, N. K., Efremova, G. G., Sigalov, M. V., Keiko, V. V., Leonov, S. B., Amosova, S. V., & Trofimov, B. A. (1981). Divinyl sulfoxide II. Vinylation and vinylsulfinylation of triorganylsilylalkanethiols by divinyl sulfoxide. Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 30(5), 864-867. https://doi.org/10.1007/BF00955301

@article{2c6739f2e44e4a70bfb34035b81bd962,

title = "Divinyl sulfoxide II. Vinylation and vinylsulfinylation of triorganylsilylalkanethiols by divinyl sulfoxide",

abstract = "1. The nucleophilic addition reaction of triorganylsilylalkanethiols to divinyl sulfoxide leads to the formation of vinyl β-(triorganylsilylalkylthio)ethyl sulfoxides. The latter, as the result of thermal dissociation are transformed into vinyl triorganylsilylalkyl sulfides (the indirect vinylation reaction). 2. The nucleophilic reaction of triorganylsilylalkanethiols with divinyl sulfoxide is accompanied by a side oxidation- reduction process and a thiylation reaction, leading to the formation of vinyl β-(triorganylsilylalkylthio)ethyl sulfides, 1,1-bis(triorganylsilylalkylthio) ethanes and vinyl triorganylsilylalkyl disulfides.",

author = "Voronkov, {M. G.} and Vlasova, {N. N.} and Kletsko, {F. P.} and Gusarova, {N. K.} and Efremova, {G. G.} and Sigalov, {M. V.} and Keiko, {V. V.} and Leonov, {S. B.} and Amosova, {S. V.} and Trofimov, {B. A.}",

year = "1981",

month = jan,

day = "1",

doi = "10.1007/BF00955301",

language = "English",

volume = "30",

pages = "864--867",

journal = "Bulletin of the Academy of Sciences of the USSR Division of Chemical Science",

issn = "0568-5230",

publisher = "Springer New York",

number = "5",

}

Voronkov, MG, Vlasova, NN, Kletsko, FP, Gusarova, NK, Efremova, GG, Sigalov, MV, Keiko, VV, Leonov, SB, Amosova, SV & Trofimov, BA 1981, 'Divinyl sulfoxide II. Vinylation and vinylsulfinylation of triorganylsilylalkanethiols by divinyl sulfoxide', Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, vol. 30, no. 5, pp. 864-867. https://doi.org/10.1007/BF00955301

TY - JOUR

T1 - Divinyl sulfoxide II. Vinylation and vinylsulfinylation of triorganylsilylalkanethiols by divinyl sulfoxide

AU - Voronkov, M. G.

AU - Vlasova, N. N.

AU - Kletsko, F. P.

AU - Gusarova, N. K.

AU - Efremova, G. G.

AU - Sigalov, M. V.

AU - Keiko, V. V.

AU - Leonov, S. B.

AU - Amosova, S. V.

AU - Trofimov, B. A.

PY - 1981/1/1

Y1 - 1981/1/1

N2 - 1. The nucleophilic addition reaction of triorganylsilylalkanethiols to divinyl sulfoxide leads to the formation of vinyl β-(triorganylsilylalkylthio)ethyl sulfoxides. The latter, as the result of thermal dissociation are transformed into vinyl triorganylsilylalkyl sulfides (the indirect vinylation reaction). 2. The nucleophilic reaction of triorganylsilylalkanethiols with divinyl sulfoxide is accompanied by a side oxidation- reduction process and a thiylation reaction, leading to the formation of vinyl β-(triorganylsilylalkylthio)ethyl sulfides, 1,1-bis(triorganylsilylalkylthio) ethanes and vinyl triorganylsilylalkyl disulfides.

AB - 1. The nucleophilic addition reaction of triorganylsilylalkanethiols to divinyl sulfoxide leads to the formation of vinyl β-(triorganylsilylalkylthio)ethyl sulfoxides. The latter, as the result of thermal dissociation are transformed into vinyl triorganylsilylalkyl sulfides (the indirect vinylation reaction). 2. The nucleophilic reaction of triorganylsilylalkanethiols with divinyl sulfoxide is accompanied by a side oxidation- reduction process and a thiylation reaction, leading to the formation of vinyl β-(triorganylsilylalkylthio)ethyl sulfides, 1,1-bis(triorganylsilylalkylthio) ethanes and vinyl triorganylsilylalkyl disulfides.

UR - http://www.scopus.com/inward/record.url?scp=34250231101&partnerID=8YFLogxK

U2 - 10.1007/BF00955301

DO - 10.1007/BF00955301

M3 - Article

AN - SCOPUS:34250231101

SN - 0568-5230

VL - 30

SP - 864

EP - 867

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 5

ER -

Divinyl sulfoxide II. Vinylation and vinylsulfinylation of triorganylsilylalkanethiols by divinyl sulfoxide

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this