Does charge carrier dimensionality increase in mixed-valence salts of tetrathiafulvalene-terminated dendrimers?

Alexander Kanibolotsky, Sophie Roquet, Michel Cariou, Philippe Leriche, Cédric Olivier Turrin, Rémi De Bettignies, Anne Marie Caminade, Jean Pierre Majoral, Vladimir Khodorkovsky, Alain Gorgues

Research output: Contribution to journalArticlepeer-review

20 Scopus citations

Abstract

In four new dendrimers terminated by 12 electroactive tetrathiafulvalenyl substituents, the tridimensional character of the inter- and intradendrimeric charge and electron transfer, and hence of the electroconductivity, is evidenced by examination of the electronic spectra of their corresponding neutral state and cation radical, dication, and mixed-valence salts, including a closed-shell anion.

Original languageEnglish
Pages (from-to)2109-2112
Number of pages4
JournalOrganic Letters
Volume6
Issue number13
DOIs
StatePublished - 24 Jun 2004

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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