Donor-stabilized silyl cations 4: N-isopropylidene hydrazides, novel bidentate ligands for penta- and hexacoordinate silicon chelates

Inna Kalikhman; Boris Gostevskii; Olga Girshberg; Sonia Krivonos; Daniel Kost

doi:10.1021/om0200914

Donor-stabilized silyl cations 4: N-isopropylidene hydrazides, novel bidentate ligands for penta- and hexacoordinate silicon chelates

Inna Kalikhman, Boris Gostevskii, Olga Girshberg, Sonia Krivonos, Daniel Kost

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

A study was performed on donor-stabilized silyl cations. The novel chelating agents derived from N-isopropylidene hydrazides, N-isopropylideneimino-O-(trimethylsilyl)acylimidates were utilized to prepare hexacoordinate dihalosilicon complexes. These complexes were unique in their trans geometry and in their facile ionization to pentacoordinate siliconium halide salts.

Original language	English
Pages (from-to)	2551-2554
Number of pages	4
Journal	Organometallics
Volume	21
Issue number	12
DOIs	https://doi.org/10.1021/om0200914
State	Published - 10 Jun 2002

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om0200914

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abstract = "A study was performed on donor-stabilized silyl cations. The novel chelating agents derived from N-isopropylidene hydrazides, N-isopropylideneimino-O-(trimethylsilyl)acylimidates were utilized to prepare hexacoordinate dihalosilicon complexes. These complexes were unique in their trans geometry and in their facile ionization to pentacoordinate siliconium halide salts.",

author = "Inna Kalikhman and Boris Gostevskii and Olga Girshberg and Sonia Krivonos and Daniel Kost",

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AU - Kalikhman, Inna

AU - Gostevskii, Boris

AU - Girshberg, Olga

AU - Krivonos, Sonia

AU - Kost, Daniel

PY - 2002/6/10

Y1 - 2002/6/10

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Donor-stabilized silyl cations 4: N-isopropylidene hydrazides, novel bidentate ligands for penta- and hexacoordinate silicon chelates

Abstract

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