Donor-stabilized silyl cations. 8. Carbon - Carbon bond formation through a novel interchelate molecular rearrangement in pentacoordinate siliconium-ion salts

Boris Gostevskii; Vadim Pestunovich; Inna Kalikhman; Akella Sivaramakrishna; Nikolaus Kocher; Stephan Deuerlein; Dirk Leusser; Dietmar Stalke; Daniel Kost

doi:10.1021/om0495751

Donor-stabilized silyl cations. 8. Carbon - Carbon bond formation through a novel interchelate molecular rearrangement in pentacoordinate siliconium-ion salts

Boris Gostevskii, Vadim Pestunovich, Inna Kalikhman, Akella Sivaramakrishna, Nikolaus Kocher, Stephan Deuerlein, Dirk Leusser, Dietmar Stalke, Daniel Kost

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

Tricyclic neutral pentacoordinate silicon complexes are formed by a novel intramolecular rearrangement of pentacoordinate bis(imino nitrogen)-chelated siliconium halide salts. The rearrangement consists of an interchelate aldol-type condensation of imine moieties, forming a new carbon-carbon bond and a third chelate ring.

Original language	English
Pages (from-to)	4346-4348
Number of pages	3
Journal	Organometallics
Volume	23
Issue number	19
DOIs	https://doi.org/10.1021/om0495751
State	Published - 13 Sep 2004

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Donor-stabilized silyl cations. 8. Carbon - Carbon bond formation through a novel interchelate molecular rearrangement in pentacoordinate siliconium-ion salts",

abstract = "Tricyclic neutral pentacoordinate silicon complexes are formed by a novel intramolecular rearrangement of pentacoordinate bis(imino nitrogen)-chelated siliconium halide salts. The rearrangement consists of an interchelate aldol-type condensation of imine moieties, forming a new carbon-carbon bond and a third chelate ring.",

author = "Boris Gostevskii and Vadim Pestunovich and Inna Kalikhman and Akella Sivaramakrishna and Nikolaus Kocher and Stephan Deuerlein and Dirk Leusser and Dietmar Stalke and Daniel Kost",

year = "2004",

month = sep,

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Gostevskii, B, Pestunovich, V, Kalikhman, I, Sivaramakrishna, A, Kocher, N, Deuerlein, S, Leusser, D, Stalke, D & Kost, D 2004, 'Donor-stabilized silyl cations. 8. Carbon - Carbon bond formation through a novel interchelate molecular rearrangement in pentacoordinate siliconium-ion salts', Organometallics, vol. 23, no. 19, pp. 4346-4348. https://doi.org/10.1021/om0495751

TY - JOUR

T1 - Donor-stabilized silyl cations. 8. Carbon - Carbon bond formation through a novel interchelate molecular rearrangement in pentacoordinate siliconium-ion salts

AU - Gostevskii, Boris

AU - Pestunovich, Vadim

AU - Kalikhman, Inna

AU - Sivaramakrishna, Akella

AU - Kocher, Nikolaus

AU - Deuerlein, Stephan

AU - Leusser, Dirk

AU - Stalke, Dietmar

AU - Kost, Daniel

PY - 2004/9/13

Y1 - 2004/9/13

N2 - Tricyclic neutral pentacoordinate silicon complexes are formed by a novel intramolecular rearrangement of pentacoordinate bis(imino nitrogen)-chelated siliconium halide salts. The rearrangement consists of an interchelate aldol-type condensation of imine moieties, forming a new carbon-carbon bond and a third chelate ring.

AB - Tricyclic neutral pentacoordinate silicon complexes are formed by a novel intramolecular rearrangement of pentacoordinate bis(imino nitrogen)-chelated siliconium halide salts. The rearrangement consists of an interchelate aldol-type condensation of imine moieties, forming a new carbon-carbon bond and a third chelate ring.

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U2 - 10.1021/om0495751

DO - 10.1021/om0495751

M3 - Article

AN - SCOPUS:4544348968

SN - 0276-7333

VL - 23

SP - 4346

EP - 4348

JO - Organometallics

JF - Organometallics

IS - 19

ER -

Donor-stabilized silyl cations. 8. Carbon - Carbon bond formation through a novel interchelate molecular rearrangement in pentacoordinate siliconium-ion salts

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