Double Rotation 23Na NMR Study of Guest-Host Interactions and Nanoscale Assemblies in Sodium Zeolite Y

R. Jelinek, S. Ozkar, G. A. Ozin

Research output: Contribution to journalArticlepeer-review

Abstract

23Na double rotation NMR (DOR) provides information on site-specific adsorption of guest molecules within the porous framework of sodium zeolite Y. Anchoring of molybdenum-hexacarbonyl to extraframework Na+ cations in particular locations within the large α-cavities is detected. Changes of the chemical environments of the Na+ cations are observed upon loading trimethylphosphine molecules. Spin-lattice relaxation measurements yield insight on dynamic aspects of the anchoring sodium cations.
Original languageEnglish
Pages (from-to)113-118
Number of pages6
JournalMRS Online Proceedings Library
Volume277
Issue number1
DOIs
StatePublished - Dec 1992
Externally publishedYes

Fingerprint

Dive into the research topics of 'Double Rotation 23Na NMR Study of Guest-Host Interactions and Nanoscale Assemblies in Sodium Zeolite Y'. Together they form a unique fingerprint.

Cite this