Drastic spectroscopic perturbations due to dynamics of linearly inactive (sequence forming) and linearly active (progression forming) Jahn-Teller modes

Benjamin Scharf; Rachel Vitenberg; Benjamin Katz; Yehuda B. Band

doi:10.1063/1.443706

Drastic spectroscopic perturbations due to dynamics of linearly inactive (sequence forming) and linearly active (progression forming) Jahn-Teller modes

Benjamin Scharf, Rachel Vitenberg, Benjamin Katz, Yehuda B. Band

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

We predict drastic changes of splittings in the v-v sequence of a linearly J-T inactive mode along a progression of a linearly J-T active mode. This phenomenon results from the mutual dynamics of the two modes. Preliminary experimental evidence is in accord with these predictions. Previously observed variations in unique splittings due to vibrational perturbations along J-T progressions resulting from asymmetric deuterations can also be explained using the theoretical analysis developed here.

Original language	English
Pages (from-to)	4903-4911
Number of pages	9
Journal	Journal of Chemical Physics
Volume	77
Issue number	10
DOIs	https://doi.org/10.1063/1.443706
State	Published - 1 Jan 1982

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

Access to Document

10.1063/1.443706

Cite this

@article{ecf15b5d721048d6908c3e6034663719,

title = "Drastic spectroscopic perturbations due to dynamics of linearly inactive (sequence forming) and linearly active (progression forming) Jahn-Teller modes",

abstract = "We predict drastic changes of splittings in the v-v sequence of a linearly J-T inactive mode along a progression of a linearly J-T active mode. This phenomenon results from the mutual dynamics of the two modes. Preliminary experimental evidence is in accord with these predictions. Previously observed variations in unique splittings due to vibrational perturbations along J-T progressions resulting from asymmetric deuterations can also be explained using the theoretical analysis developed here.",

author = "Benjamin Scharf and Rachel Vitenberg and Benjamin Katz and Band, {Yehuda B.}",

year = "1982",

month = jan,

day = "1",

doi = "10.1063/1.443706",

language = "English",

volume = "77",

pages = "4903--4911",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "10",

}

TY - JOUR

T1 - Drastic spectroscopic perturbations due to dynamics of linearly inactive (sequence forming) and linearly active (progression forming) Jahn-Teller modes

AU - Scharf, Benjamin

AU - Vitenberg, Rachel

AU - Katz, Benjamin

AU - Band, Yehuda B.

PY - 1982/1/1

Y1 - 1982/1/1

N2 - We predict drastic changes of splittings in the v-v sequence of a linearly J-T inactive mode along a progression of a linearly J-T active mode. This phenomenon results from the mutual dynamics of the two modes. Preliminary experimental evidence is in accord with these predictions. Previously observed variations in unique splittings due to vibrational perturbations along J-T progressions resulting from asymmetric deuterations can also be explained using the theoretical analysis developed here.

AB - We predict drastic changes of splittings in the v-v sequence of a linearly J-T inactive mode along a progression of a linearly J-T active mode. This phenomenon results from the mutual dynamics of the two modes. Preliminary experimental evidence is in accord with these predictions. Previously observed variations in unique splittings due to vibrational perturbations along J-T progressions resulting from asymmetric deuterations can also be explained using the theoretical analysis developed here.

UR - http://www.scopus.com/inward/record.url?scp=3843108151&partnerID=8YFLogxK

U2 - 10.1063/1.443706

DO - 10.1063/1.443706

M3 - Article

AN - SCOPUS:3843108151

SN - 0021-9606

VL - 77

SP - 4903

EP - 4911

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 10

ER -

Drastic spectroscopic perturbations due to dynamics of linearly inactive (sequence forming) and linearly active (progression forming) Jahn-Teller modes

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this