Effect of NVP, HEMA, and Bis-GMA Grafting on Thermal and Physical Properties of Poly(AA-co-IA)

Mayuri Gupta; A. K. Tyagi; Manoj Raula

doi:10.1002/masy.70000

Effect of NVP, HEMA, and Bis-GMA Grafting on Thermal and Physical Properties of Poly(AA-co-IA)

Mayuri Gupta, A. K. Tyagi, Manoj Raula

Research output: Contribution to journal › Article › peer-review

Abstract

In this work, we report the grafting of monomers, such as bisphenol-A-glycidyl methacrylate (bis-GMA), N-vinylpyrrolidone (NVP), and 2-hydroxy ethyl methacrylate (HEMA), on the copolymer of acrylic and itaconic acid [poly (AA-co-IA)] using simple condensation polymerization technique. The resultant graft copolymers are characterized by FTIR, TGA-DTG, DSC, and SEM analysis. All these studies confirm the formation of grafted copolymers. We have varied the monomer concentration ratios and catalyst concentrations to study the variations in degree of grafting. All the synthesized graft copolymers are then mixed with HEMA and camphorquinone to make an LED light-curable dental polymer. Thermal and physical properties, such as the strength and hardness of the cured grafted copolymers, are studied in detail and found that the developed composite is 35% stronger in terms of compressive strength as compared to commercial samples.

Original language	English
Article number	70000
Journal	Macromolecular Symposia
Volume	414
Issue number	2
DOIs	https://doi.org/10.1002/masy.70000
State	Published - 1 Apr 2025
Externally published	Yes

Keywords

Grafted copolymer
Physical properties
Poly(AA-co-IA)
Thermal properties

ASJC Scopus subject areas

Condensed Matter Physics
Organic Chemistry
Polymers and Plastics
Materials Chemistry

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10.1002/masy.70000

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title = "Effect of NVP, HEMA, and Bis-GMA Grafting on Thermal and Physical Properties of Poly(AA-co-IA)",

abstract = "In this work, we report the grafting of monomers, such as bisphenol-A-glycidyl methacrylate (bis-GMA), N-vinylpyrrolidone (NVP), and 2-hydroxy ethyl methacrylate (HEMA), on the copolymer of acrylic and itaconic acid [poly (AA-co-IA)] using simple condensation polymerization technique. The resultant graft copolymers are characterized by FTIR, TGA-DTG, DSC, and SEM analysis. All these studies confirm the formation of grafted copolymers. We have varied the monomer concentration ratios and catalyst concentrations to study the variations in degree of grafting. All the synthesized graft copolymers are then mixed with HEMA and camphorquinone to make an LED light-curable dental polymer. Thermal and physical properties, such as the strength and hardness of the cured grafted copolymers, are studied in detail and found that the developed composite is 35\% stronger in terms of compressive strength as compared to commercial samples.",

keywords = "Grafted copolymer, Physical properties, Poly(AA-co-IA), Thermal properties",

author = "Mayuri Gupta and Tyagi, \{A. K.\} and Manoj Raula",

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doi = "10.1002/masy.70000",

language = "English",

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T1 - Effect of NVP, HEMA, and Bis-GMA Grafting on Thermal and Physical Properties of Poly(AA-co-IA)

AU - Gupta, Mayuri

AU - Tyagi, A. K.

AU - Raula, Manoj

PY - 2025/4/1

Y1 - 2025/4/1

N2 - In this work, we report the grafting of monomers, such as bisphenol-A-glycidyl methacrylate (bis-GMA), N-vinylpyrrolidone (NVP), and 2-hydroxy ethyl methacrylate (HEMA), on the copolymer of acrylic and itaconic acid [poly (AA-co-IA)] using simple condensation polymerization technique. The resultant graft copolymers are characterized by FTIR, TGA-DTG, DSC, and SEM analysis. All these studies confirm the formation of grafted copolymers. We have varied the monomer concentration ratios and catalyst concentrations to study the variations in degree of grafting. All the synthesized graft copolymers are then mixed with HEMA and camphorquinone to make an LED light-curable dental polymer. Thermal and physical properties, such as the strength and hardness of the cured grafted copolymers, are studied in detail and found that the developed composite is 35% stronger in terms of compressive strength as compared to commercial samples.

AB - In this work, we report the grafting of monomers, such as bisphenol-A-glycidyl methacrylate (bis-GMA), N-vinylpyrrolidone (NVP), and 2-hydroxy ethyl methacrylate (HEMA), on the copolymer of acrylic and itaconic acid [poly (AA-co-IA)] using simple condensation polymerization technique. The resultant graft copolymers are characterized by FTIR, TGA-DTG, DSC, and SEM analysis. All these studies confirm the formation of grafted copolymers. We have varied the monomer concentration ratios and catalyst concentrations to study the variations in degree of grafting. All the synthesized graft copolymers are then mixed with HEMA and camphorquinone to make an LED light-curable dental polymer. Thermal and physical properties, such as the strength and hardness of the cured grafted copolymers, are studied in detail and found that the developed composite is 35% stronger in terms of compressive strength as compared to commercial samples.

KW - Grafted copolymer

KW - Physical properties

KW - Poly(AA-co-IA)

KW - Thermal properties

UR - https://www.scopus.com/pages/publications/105003162924

U2 - 10.1002/masy.70000

DO - 10.1002/masy.70000

M3 - Article

AN - SCOPUS:105003162924

SN - 1022-1360

VL - 414

JO - Macromolecular Symposia

JF - Macromolecular Symposia

IS - 2

M1 - 70000

ER -

Effect of NVP, HEMA, and Bis-GMA Grafting on Thermal and Physical Properties of Poly(AA-co-IA)

Abstract

Keywords

ASJC Scopus subject areas

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