Abstract
Sound velocities in aqueous 0.1 mol·kg−1, 0.5 mol·kg−1 and 1.0 mol·kg−1 solutions of NaCl, NaBr, NaI, KCl, KBr, KI, RbCl and RbI were measured at 1 K intervals from T = (278.15 to 353.15) K. Determined sound velocities and densities served to determine the isentropic and isothermal compressibility coefficients, the apparent molar compressibilities, the apparent molar volumes, the isochoric thermal pressure coefficients, cubic expansion coefficients, changes of heat capacities with volume and with pressure, and the hydration numbers. In addition were evaluated the ultrasonic relaxation times and corresponding thermodynamic functions of the activation of the viscous process. Determined parameters are qualitatively correlated with changes in the structure of water when alkali metal halides are dissolved in it.
Original language | English |
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Pages (from-to) | 1263-1284 |
Number of pages | 22 |
Journal | Journal of Molecular Liquids |
Volume | 242 |
DOIs | |
State | Published - 1 Sep 2017 |
Keywords
- Alkali metal halides
- Apparent molar compressibilities and apparent molar volumes
- Changes of in heat capacities with volume and pressure
- Cubic expansion coefficients
- Densities
- Isochoric thermal pressure coefficients
- Isothermal and isentropic compressibilities
- Sound velocities
- Structure of aqueous solutions of alkali metal halides
- Thermodynamic functions of the activation of the viscous process
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Atomic and Molecular Physics, and Optics
- Condensed Matter Physics
- Spectroscopy
- Physical and Theoretical Chemistry
- Materials Chemistry