Electric-dipole increase in NMR intensity in mixed-valence complexes

M. A. Ivanov; V. Ya Mitrofanov; L. D. Fal'Kovskaya; A. Ya Fishman; B. S. Tsukerblat

doi:10.1134/1.1881728

Electric-dipole increase in NMR intensity in mixed-valence complexes

M. A. Ivanov, V. Ya Mitrofanov, L. D. Fal'Kovskaya, A. Ya Fishman, B. S. Tsukerblat

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The possibility of a considerable increase in NMR intensity has been shown for absorption on mixed-valence 3d ions in magnetically ordered crystals. This effect is determined by the high intensity of electric dipole transitions between the ground and low excited levels of a mixed-valence complex, as well as by the existence of the unfrozen orbital angular momentum in such complexes, which mixes nuclear and electron states.

Original language	English
Pages (from-to)	15-18
Number of pages	4
Journal	JETP Letters
Volume	81
Issue number	1
DOIs	https://doi.org/10.1134/1.1881728
State	Published - 1 Jan 2005

ASJC Scopus subject areas

Physics and Astronomy (miscellaneous)

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10.1134/1.1881728

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title = "Electric-dipole increase in NMR intensity in mixed-valence complexes",

abstract = "The possibility of a considerable increase in NMR intensity has been shown for absorption on mixed-valence 3d ions in magnetically ordered crystals. This effect is determined by the high intensity of electric dipole transitions between the ground and low excited levels of a mixed-valence complex, as well as by the existence of the unfrozen orbital angular momentum in such complexes, which mixes nuclear and electron states.",

author = "Ivanov, {M. A.} and Mitrofanov, {V. Ya} and Fal'Kovskaya, {L. D.} and Fishman, {A. Ya} and Tsukerblat, {B. S.}",

note = "Funding Information: This work was supported by the Russian Foundation for Basic Research.",

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AU - Ivanov, M. A.

AU - Mitrofanov, V. Ya

AU - Fal'Kovskaya, L. D.

AU - Fishman, A. Ya

AU - Tsukerblat, B. S.

N1 - Funding Information: This work was supported by the Russian Foundation for Basic Research.

PY - 2005/1/1

Y1 - 2005/1/1

N2 - The possibility of a considerable increase in NMR intensity has been shown for absorption on mixed-valence 3d ions in magnetically ordered crystals. This effect is determined by the high intensity of electric dipole transitions between the ground and low excited levels of a mixed-valence complex, as well as by the existence of the unfrozen orbital angular momentum in such complexes, which mixes nuclear and electron states.

AB - The possibility of a considerable increase in NMR intensity has been shown for absorption on mixed-valence 3d ions in magnetically ordered crystals. This effect is determined by the high intensity of electric dipole transitions between the ground and low excited levels of a mixed-valence complex, as well as by the existence of the unfrozen orbital angular momentum in such complexes, which mixes nuclear and electron states.

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DO - 10.1134/1.1881728

M3 - Article

AN - SCOPUS:17544379008

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Electric-dipole increase in NMR intensity in mixed-valence complexes

Abstract

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