Electrochemical oxidation germacyclopentadienes (germoles)

Anand Dhiman; Zeng Rong Zhang; Robert West; James Y. Becker

doi:10.1016/j.jelechem.2004.06.028

Electrochemical oxidation germacyclopentadienes (germoles)

Anand Dhiman
, Zeng Rong Zhang
, Robert West
, James Y. Becker

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The electrochemical oxidation of five germole derivatives: 1,1-bis(trimethylsilyl)-2,3,4,5-tetraphenyl-1-germacyclopentadiene (I), 1,1-dimethyl-2,3,4,5-tetraphenyl-1-germacyclopentadiene (II), 1-methyl-1-chloro-2,3,4,5-tetraphenyl-1-germacyclopentadiene (III), 1,1-dichloro-2,3,4,5-tetraphenyl-1-germacyclopentadiene (IV) and a bicyclic compound (V) 1,1′-dimethyl-2,2′,3,3′,4,4′,5,5′- octaphenyl bisilole, bonded through a Si-Si bond, has been investigated, both by cyclic voltammetry and controlled-potential electrolysis. The effects of the nature of electrolyte, atmosphere and substituents attached to the germanium atom in the germacyclopentadiene ring on the outcome of the electrochemical oxidation are discussed.

Original language	English
Pages (from-to)	139-146
Number of pages	8
Journal	Journal of Electroanalytical Chemistry
Volume	573
Issue number	1
DOIs	https://doi.org/10.1016/j.jelechem.2004.06.028
State	Published - 15 Nov 2004

Keywords

Cyclic voltammetry
Electrochemical oxidation
Germacyclopentadienes
Germoles

ASJC Scopus subject areas

Analytical Chemistry
General Chemical Engineering
Electrochemistry

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10.1016/j.jelechem.2004.06.028

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@article{734c9251a1f14dc5bbc124a5981ff09b,

title = "Electrochemical oxidation germacyclopentadienes (germoles)",

abstract = "The electrochemical oxidation of five germole derivatives: 1,1-bis(trimethylsilyl)-2,3,4,5-tetraphenyl-1-germacyclopentadiene (I), 1,1-dimethyl-2,3,4,5-tetraphenyl-1-germacyclopentadiene (II), 1-methyl-1-chloro-2,3,4,5-tetraphenyl-1-germacyclopentadiene (III), 1,1-dichloro-2,3,4,5-tetraphenyl-1-germacyclopentadiene (IV) and a bicyclic compound (V) 1,1′-dimethyl-2,2′,3,3′,4,4′,5,5′- octaphenyl bisilole, bonded through a Si-Si bond, has been investigated, both by cyclic voltammetry and controlled-potential electrolysis. The effects of the nature of electrolyte, atmosphere and substituents attached to the germanium atom in the germacyclopentadiene ring on the outcome of the electrochemical oxidation are discussed.",

keywords = "Cyclic voltammetry, Electrochemical oxidation, Germacyclopentadienes, Germoles",

author = "Anand Dhiman and Zhang, \{Zeng Rong\} and Robert West and Becker, \{James Y.\}",

note = "Funding Information: The authors are grateful to “VATAT” (through the Israel Council for Higher Education) for granting a post-doctoral fellowship to Dr. A. Dhiman.",

year = "2004",

month = nov,

day = "15",

doi = "10.1016/j.jelechem.2004.06.028",

language = "English",

volume = "573",

pages = "139--146",

journal = "Journal of Electroanalytical Chemistry",

issn = "1572-6657",

publisher = "Elsevier B.V.",

number = "1",

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TY - JOUR

T1 - Electrochemical oxidation germacyclopentadienes (germoles)

AU - Dhiman, Anand

AU - Zhang, Zeng Rong

AU - West, Robert

AU - Becker, James Y.

N1 - Funding Information: The authors are grateful to “VATAT” (through the Israel Council for Higher Education) for granting a post-doctoral fellowship to Dr. A. Dhiman.

PY - 2004/11/15

Y1 - 2004/11/15

N2 - The electrochemical oxidation of five germole derivatives: 1,1-bis(trimethylsilyl)-2,3,4,5-tetraphenyl-1-germacyclopentadiene (I), 1,1-dimethyl-2,3,4,5-tetraphenyl-1-germacyclopentadiene (II), 1-methyl-1-chloro-2,3,4,5-tetraphenyl-1-germacyclopentadiene (III), 1,1-dichloro-2,3,4,5-tetraphenyl-1-germacyclopentadiene (IV) and a bicyclic compound (V) 1,1′-dimethyl-2,2′,3,3′,4,4′,5,5′- octaphenyl bisilole, bonded through a Si-Si bond, has been investigated, both by cyclic voltammetry and controlled-potential electrolysis. The effects of the nature of electrolyte, atmosphere and substituents attached to the germanium atom in the germacyclopentadiene ring on the outcome of the electrochemical oxidation are discussed.

AB - The electrochemical oxidation of five germole derivatives: 1,1-bis(trimethylsilyl)-2,3,4,5-tetraphenyl-1-germacyclopentadiene (I), 1,1-dimethyl-2,3,4,5-tetraphenyl-1-germacyclopentadiene (II), 1-methyl-1-chloro-2,3,4,5-tetraphenyl-1-germacyclopentadiene (III), 1,1-dichloro-2,3,4,5-tetraphenyl-1-germacyclopentadiene (IV) and a bicyclic compound (V) 1,1′-dimethyl-2,2′,3,3′,4,4′,5,5′- octaphenyl bisilole, bonded through a Si-Si bond, has been investigated, both by cyclic voltammetry and controlled-potential electrolysis. The effects of the nature of electrolyte, atmosphere and substituents attached to the germanium atom in the germacyclopentadiene ring on the outcome of the electrochemical oxidation are discussed.

KW - Cyclic voltammetry

KW - Electrochemical oxidation

KW - Germacyclopentadienes

KW - Germoles

UR - https://www.scopus.com/pages/publications/6344223355

U2 - 10.1016/j.jelechem.2004.06.028

DO - 10.1016/j.jelechem.2004.06.028

M3 - Article

AN - SCOPUS:6344223355

SN - 1572-6657

VL - 573

SP - 139

EP - 146

JO - Journal of Electroanalytical Chemistry

JF - Journal of Electroanalytical Chemistry

IS - 1

ER -

Electrochemical oxidation germacyclopentadienes (germoles)

Abstract

Keywords

ASJC Scopus subject areas

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