Electrochemical oxidation of a silole: 1, 1-bis(trimethylsilyl)-2, 3, 4, 5-tetraphenyl-1-silacyclopentadiene

Z. R. Zhang; J. Y. Becker; R. West

doi:10.1016/S0022-0728(01)00365-5

Electrochemical oxidation of a silole: 1, 1-bis(trimethylsilyl)-2, 3, 4, 5-tetraphenyl-1-silacyclopentadiene

Z. R. Zhang, J. Y. Becker, R. West

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The electrochemical oxidation of 1, 1-bis(trimethylsilyl)-2, 3, 4, 5-tetraphenyl-1-silacyclopentadiene has been investigated under different conditions. The effect of electrolyte, electrode material and atmosphere on the outcome of its electrochemical oxidation are discussed. Under all conditions studied, the silole derivative studied undergoes ring-opening, sometimes with the extrusion of the silicon moiety.

Original language	English
Pages (from-to)	49-54
Number of pages	6
Journal	Journal of Electroanalytical Chemistry
Volume	507
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-0728(01)00365-5
State	Published - 13 Jul 2001

Keywords

Cyclic voltammetry
Electrochemical oxidation
Silacyclopentadiene
Silole

ASJC Scopus subject areas

Analytical Chemistry
General Chemical Engineering
Electrochemistry

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10.1016/S0022-0728(01)00365-5

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title = "Electrochemical oxidation of a silole: 1, 1-bis(trimethylsilyl)-2, 3, 4, 5-tetraphenyl-1-silacyclopentadiene",

abstract = "The electrochemical oxidation of 1, 1-bis(trimethylsilyl)-2, 3, 4, 5-tetraphenyl-1-silacyclopentadiene has been investigated under different conditions. The effect of electrolyte, electrode material and atmosphere on the outcome of its electrochemical oxidation are discussed. Under all conditions studied, the silole derivative studied undergoes ring-opening, sometimes with the extrusion of the silicon moiety.",

keywords = "Cyclic voltammetry, Electrochemical oxidation, Silacyclopentadiene, Silole",

author = "Zhang, {Z. R.} and Becker, {J. Y.} and R. West",

year = "2001",

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T1 - Electrochemical oxidation of a silole

T2 - 1, 1-bis(trimethylsilyl)-2, 3, 4, 5-tetraphenyl-1-silacyclopentadiene

AU - Zhang, Z. R.

AU - Becker, J. Y.

AU - West, R.

PY - 2001/7/13

Y1 - 2001/7/13

N2 - The electrochemical oxidation of 1, 1-bis(trimethylsilyl)-2, 3, 4, 5-tetraphenyl-1-silacyclopentadiene has been investigated under different conditions. The effect of electrolyte, electrode material and atmosphere on the outcome of its electrochemical oxidation are discussed. Under all conditions studied, the silole derivative studied undergoes ring-opening, sometimes with the extrusion of the silicon moiety.

AB - The electrochemical oxidation of 1, 1-bis(trimethylsilyl)-2, 3, 4, 5-tetraphenyl-1-silacyclopentadiene has been investigated under different conditions. The effect of electrolyte, electrode material and atmosphere on the outcome of its electrochemical oxidation are discussed. Under all conditions studied, the silole derivative studied undergoes ring-opening, sometimes with the extrusion of the silicon moiety.

KW - Cyclic voltammetry

KW - Electrochemical oxidation

KW - Silacyclopentadiene

KW - Silole

UR - http://www.scopus.com/inward/record.url?scp=0035854247&partnerID=8YFLogxK

U2 - 10.1016/S0022-0728(01)00365-5

DO - 10.1016/S0022-0728(01)00365-5

M3 - Article

AN - SCOPUS:0035854247

SN - 0022-0728

VL - 507

SP - 49

EP - 54

JO - Journal of Electroanalytical Chemistry

JF - Journal of Electroanalytical Chemistry

IS - 1-2

ER -

Electrochemical oxidation of a silole: 1, 1-bis(trimethylsilyl)-2, 3, 4, 5-tetraphenyl-1-silacyclopentadiene

Abstract

Keywords

ASJC Scopus subject areas

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