Electrochemical oxidation of DECA-n-propylcyclo-pentasilane [(n-Pr)2Si]5

J. Y. Becker; M. Q. Shen; R. West

doi:10.1016/0013-4686(95)00267-I

Electrochemical oxidation of DECA-n-propylcyclo-pentasilane [(n-Pr)₂Si]₅

J. Y. Becker, M. Q. Shen, R. West

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The electrochemical oxidation of a cyclic peralkylsilane derivative,[(n-Pr)₂Si]₅ (I), in dichloromethane in the presence of ClO₄^- or AcO^- salts, leads to both oxygen insertion and ring-opening processes, to form mainly cyclic and linear siloxanes. The latter contain various groups at their terminal positions: OH, AcO, CH₂CN or n-propyl.

Original language	English
Pages (from-to)	2775-2778
Number of pages	4
Journal	Electrochimica Acta
Volume	40
Issue number	17
DOIs	https://doi.org/10.1016/0013-4686(95)00267-I
State	Published - 1 Jan 1995

Keywords

cyclic and linear siloxanes
deca-n-propylcyclopentasilane
electrochemical oxidation
oxygen insertion
ring opening

ASJC Scopus subject areas

General Chemical Engineering
Electrochemistry

Access to Document

10.1016/0013-4686(95)00267-I

Cite this

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title = "Electrochemical oxidation of DECA-n-propylcyclo-pentasilane [(n-Pr)2Si]5",

abstract = "The electrochemical oxidation of a cyclic peralkylsilane derivative,[(n-Pr)2Si]5 (I), in dichloromethane in the presence of ClO4- or AcO- salts, leads to both oxygen insertion and ring-opening processes, to form mainly cyclic and linear siloxanes. The latter contain various groups at their terminal positions: OH, AcO, CH2CN or n-propyl.",

keywords = "cyclic and linear siloxanes, deca-n-propylcyclopentasilane, electrochemical oxidation, oxygen insertion, ring opening",

author = "Becker, {J. Y.} and Shen, {M. Q.} and R. West",

year = "1995",

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T1 - Electrochemical oxidation of DECA-n-propylcyclo-pentasilane [(n-Pr)2Si]5

AU - Becker, J. Y.

AU - Shen, M. Q.

AU - West, R.

PY - 1995/1/1

Y1 - 1995/1/1

N2 - The electrochemical oxidation of a cyclic peralkylsilane derivative,[(n-Pr)2Si]5 (I), in dichloromethane in the presence of ClO4- or AcO- salts, leads to both oxygen insertion and ring-opening processes, to form mainly cyclic and linear siloxanes. The latter contain various groups at their terminal positions: OH, AcO, CH2CN or n-propyl.

AB - The electrochemical oxidation of a cyclic peralkylsilane derivative,[(n-Pr)2Si]5 (I), in dichloromethane in the presence of ClO4- or AcO- salts, leads to both oxygen insertion and ring-opening processes, to form mainly cyclic and linear siloxanes. The latter contain various groups at their terminal positions: OH, AcO, CH2CN or n-propyl.

KW - cyclic and linear siloxanes

KW - deca-n-propylcyclopentasilane

KW - electrochemical oxidation

KW - oxygen insertion

KW - ring opening

UR - http://www.scopus.com/inward/record.url?scp=0000772240&partnerID=8YFLogxK

U2 - 10.1016/0013-4686(95)00267-I

DO - 10.1016/0013-4686(95)00267-I

M3 - Article

AN - SCOPUS:0000772240

SN - 0013-4686

VL - 40

SP - 2775

EP - 2778

JO - Electrochimica Acta

JF - Electrochimica Acta

IS - 17

ER -