Electrochemical synthesis of 1,2-disilylethanes from α-silylacetic acids

Alex V. Shtelman; James Y. Becker

doi:10.1021/jo200254z

Electrochemical synthesis of 1,2-disilylethanes from α-silylacetic acids

Alex V. Shtelman, James Y. Becker

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

The synthesis of 1,2-disilylethanes [R₁R₂R ₃Si(CH₂)₂SiR₁R₂R ₃] is usually conducted by using noble metal reagents or catalysts. This work describes a new electrochemical synthetic method for their preparation in good yields by oxidation of α-silylacetic acids at Pt anodes (Kolbe electrolysis). Most of the reported synthesized 1,2-disilylethanes in this work are unknown.

Original language	English
Pages (from-to)	4710-4714
Number of pages	5
Journal	Journal of Organic Chemistry
Volume	76
Issue number	11
DOIs	https://doi.org/10.1021/jo200254z
State	Published - 3 Jun 2011

ASJC Scopus subject areas

Organic Chemistry

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10.1021/jo200254z

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title = "Electrochemical synthesis of 1,2-disilylethanes from α-silylacetic acids",

abstract = "The synthesis of 1,2-disilylethanes [R1R2R 3Si(CH2)2SiR1R2R 3] is usually conducted by using noble metal reagents or catalysts. This work describes a new electrochemical synthetic method for their preparation in good yields by oxidation of α-silylacetic acids at Pt anodes (Kolbe electrolysis). Most of the reported synthesized 1,2-disilylethanes in this work are unknown.",

author = "Shtelman, {Alex V.} and Becker, {James Y.}",

year = "2011",

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journal = "Journal of Organic Chemistry",

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T1 - Electrochemical synthesis of 1,2-disilylethanes from α-silylacetic acids

AU - Shtelman, Alex V.

AU - Becker, James Y.

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Y1 - 2011/6/3

N2 - The synthesis of 1,2-disilylethanes [R1R2R 3Si(CH2)2SiR1R2R 3] is usually conducted by using noble metal reagents or catalysts. This work describes a new electrochemical synthetic method for their preparation in good yields by oxidation of α-silylacetic acids at Pt anodes (Kolbe electrolysis). Most of the reported synthesized 1,2-disilylethanes in this work are unknown.

AB - The synthesis of 1,2-disilylethanes [R1R2R 3Si(CH2)2SiR1R2R 3] is usually conducted by using noble metal reagents or catalysts. This work describes a new electrochemical synthetic method for their preparation in good yields by oxidation of α-silylacetic acids at Pt anodes (Kolbe electrolysis). Most of the reported synthesized 1,2-disilylethanes in this work are unknown.

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U2 - 10.1021/jo200254z

DO - 10.1021/jo200254z

M3 - Article

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JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

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ER -

Electrochemical synthesis of 1,2-disilylethanes from α-silylacetic acids

Abstract

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