Electrochemical synthesis of 1,2-disilylethanes from α-silylacetic acids

Alex V. Shtelman, James Y. Becker

Research output: Contribution to journalArticlepeer-review

18 Scopus citations

Abstract

The synthesis of 1,2-disilylethanes [R1R2R 3Si(CH2)2SiR1R2R 3] is usually conducted by using noble metal reagents or catalysts. This work describes a new electrochemical synthetic method for their preparation in good yields by oxidation of α-silylacetic acids at Pt anodes (Kolbe electrolysis). Most of the reported synthesized 1,2-disilylethanes in this work are unknown.

Original languageEnglish
Pages (from-to)4710-4714
Number of pages5
JournalJournal of Organic Chemistry
Volume76
Issue number11
DOIs
StatePublished - 3 Jun 2011

ASJC Scopus subject areas

  • Organic Chemistry

Fingerprint

Dive into the research topics of 'Electrochemical synthesis of 1,2-disilylethanes from α-silylacetic acids'. Together they form a unique fingerprint.

Cite this