Abstract
The results of electrochemical investigations by cyclic voltammetry and density functional computations of new saturated (2, 3) and unsaturated N-heterocyclic silylenes (5, 6) are described and compared with the previously known N-heterocyclic silylenes (1, 4). Good correlations have been found between experimental oxidation potentials of saturated 1-3 and unsaturated 4-6 with those of density functional calculations of the electronic properties of these divalent silicon derivatives.
Original language | English |
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Pages (from-to) | 1603-1606 |
Number of pages | 4 |
Journal | Organometallics |
Volume | 29 |
Issue number | 7 |
DOIs | |
State | Published - 12 Apr 2010 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry