Electrochemistry and MO computations of saturated and unsaturated n-heterocyclic silylenes

Patrick Zark, Thomas Müller, Robert West, Kendrekar Pravinkumar, James Y. Becker

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

The results of electrochemical investigations by cyclic voltammetry and density functional computations of new saturated (2, 3) and unsaturated N-heterocyclic silylenes (5, 6) are described and compared with the previously known N-heterocyclic silylenes (1, 4). Good correlations have been found between experimental oxidation potentials of saturated 1-3 and unsaturated 4-6 with those of density functional calculations of the electronic properties of these divalent silicon derivatives.

Original languageEnglish
Pages (from-to)1603-1606
Number of pages4
JournalOrganometallics
Volume29
Issue number7
DOIs
StatePublished - 12 Apr 2010

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